C. H. Bamford9780444406736, 0444406735, 9780080867960
Table of contents :
Cover Page……Page 1
Title: Comprehensive Chemical Kinetics, Volume 1 – THE PRACTICE OF KINETICS……Page 4
ISBN 0444406735……Page 5
ADVISORY BOARD……Page 6
Preface……Page 8
1 Experimental methods for the study of slow reactions……Page 10
2 Experimental methods for the study of fast reactions……Page 11
3 Experimental methods for the study of heterogeneous reactions……Page 12
5 The treatment of experimental data……Page 13
1. Introduction……Page 16
2. Determination of a Mechanism……Page 17
3. Apparatus……Page 21
4. Analysis……Page 86
References……Page 119
Introduction……Page 127
1. Flash Photolysis and Pulse Radiolysis……Page 133
2. Shock Tube and Abiabatic Compression……Page 138
3. Chemical Relaxation Methods……Page 143
4. Spectral Line-Broadening……Page 157
5. Fluorescence Quenching……Page 167
6. Electrochemical Methods……Page 172
7. Flow Methods……Page 177
8. Flames……Page 182
9. Molecular Beams……Page 187
References……Page 191
2. The Solid–Gas Interface……Page 195
3. The Solid–Liquid Interface……Page 264
4. The Solid–Solid Interface……Page 269
5. The Liquid–Gas Interface……Page 278
References……Page 285
1. Introduction……Page 294
2. Classical Spectroscopy……Page 299
3. Mass Spectrometry……Page 309
4. ESR Spectrometry……Page 323
5. ‘Chemical’ Methods……Page 329
6. Miscellaneous Physical Techniques……Page 339
7. Electrical Methods for Charged Species……Page 343
8. Trapped Radicals……Page 346
References……Page 351
1. Introduction……Page 358
2. Testing the Data for Consistency with Equations of the Type–d[A]/dt=k[A]a [B]b……Page 363
3. Testing the Data for Consistency with Complicated Rate Expressions……Page 409
4. Elucidating the Dependence of the Rate Coefficient(s) on Temperature, Concentration of Catalyst, and Ionic Strength……Page 418
References……Page 422
Appendix 1……Page 423
Appendix 2……Page 424
Appendix 3……Page 434
Appendix 4……Page 435
A……Page 437
B……Page 438
C……Page 439
D……Page 442
E……Page 444
F……Page 445
H……Page 447
I……Page 449
M……Page 451
N……Page 453
O……Page 455
P……Page 456
Q……Page 458
R……Page 459
S……Page 460
T……Page 463
V……Page 464
Z……Page 465
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