High temperature properties and thermal decomposition of inorganic salts with oxyanions

Kurt H. Stern0849302560, 9780849302565

Twenty years ago author Kurt Stern produced four monographs for the National Bureau of Standards on the high-temperature properties of inorganic salts containing oxyanions. Although relied upon by scientists and engineers around the world, these monographs have now become increasingly difficult to access and increasingly outdated. High Temperature Properties and Thermal Decomposition of Inorganic Salts with Oxyanions unifies, expands upon, and brings up-to-date those standard-setting documents. It offers both qualitative and quantitative information on the behavior and properties of approximately 300 compounds, complete with thermodynamic tables of decomposition equilibria and information regarding decomposition kinetics. For each class of compounds, an existence chart in the form of a periodic table tells you at a glance which compounds are known to exist, those whose existence is uncertain, and those about which nothing is known. Supplementary tables give information about phase transitions and densities in both solid and liquid phases. Within this single volume, the author provides a comprehensive, critical review of the high-temperature properties of all the major classes of inorganic salts with oxyanions. If you work with materials or processes that involve salts at elevated temperatures, you now have an authoritative resource that obviates the need to perform extensive literature searches, data evaluations, and thermodynamic calculations-and saves you time.

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Table of contents :
High Temperature Properties and Thermal Decomposition of Inorganic Salts with Oxyanions……Page 2
Preface……Page 4
The Author……Page 5
Acknowledgments……Page 6
Contents……Page 7
1.1 GENERAL……Page 17
Table of Contents……Page 0
1.2 EQUILIBRIUM CALCULATIONS……Page 18
1.4 DENSITY……Page 19
1.5.2 M ECHANISM OF E NDOTHERMIC S OLID -S TATE D ECOMPOSITION……Page 20
1.5.2.1.1 Nucleus Formation……Page 21
1.5.2.2 Growth of Nuclei……Page 22
1.5.2.3 Surface Area Changes Decomposition……Page 24
1.5.3 THE EFFECT OF PRESSURE ON RATE……Page 25
1.5.4 ACTIVATION ENERGY……Page 27
1.5.6 THE EFFECT OF HEAT TRANSFER ON RATE……Page 28
REFERENCES……Page 29
2.1.2 G ENERAL F EATURES OF C ARBONATE D ECOMPOSITION……Page 31
2.2 CO, CO 2 , AND O 2……Page 32
2.3.6 C OBALT……Page 33
2.3.9 L EAD……Page 34
2.3.12 MANGANESE……Page 35
2.3.16 RARE EARTHS……Page 36
2.3.20 STRONTIUM……Page 37
2.3.22 ZINC……Page 38
REFERENCES……Page 66
3.2.1 B ARIUM……Page 68
3.2.6 I RON……Page 69
3.2.12 R ARE E ARTHS……Page 70
3.2.16 ZINC……Page 71
REFERENCES……Page 73
4.2 DECOMPOSITION EQUILIBRIA……Page 74
4.3.4 B ERYLLIUM……Page 75
4.3.9 C HROMIUM……Page 76
4.3.11 COPPER……Page 77
4.3.15 IRON……Page 78
4.3.19 MANGANESE……Page 80
4.3.23 RADIUM……Page 81
4.3.33 SAMARIUM……Page 83
4.3.41 SODIUM……Page 84
4.3.47 TITANIUM……Page 85
4.3.50 ZINC……Page 86
4.3.51 ZIRCONIUM……Page 87
REFERENCES……Page 147
5.2 THE NITRITES……Page 150
5.3.1 G ENERAL……Page 151
5.3.2 D ECOMPOSITION E QUILIBRIA……Page 152
5.4.2.1 Ba(NO2)2……Page 154
5.4.3 BERYLLIUM……Page 155
5.4.6.1 Ca(NO2)2……Page 156
5.4.8 CHROMIUM……Page 157
5.4.13 HAFNIUM……Page 158
5.4.16.2 Pb(NO3)2……Page 159
5.4.17.2 LiNO3……Page 160
5.4.20.3 Hg(NO3)2……Page 161
5.4.23.1 KNO2……Page 162
5.4.25.1 Nitrites……Page 163
5.4.26.2 RbNO3……Page 164
5.4.29.1 NaNO2……Page 165
5.4.30.1 Sr(NO2)2……Page 166
5.4.31.1 TlNO2……Page 167
5.4.36 ZIRCONIUM……Page 168
REFERENCES……Page 196
6.4 CHEMISTRY OF THE HALOGEN-OXYSALTS……Page 200
REFERENCES……Page 202
7.2.1 C HLORITES……Page 203
7.2.2 C HLORATES……Page 204
7.2.3 P ERCHLORATES……Page 205
7.3.2.1 Ba(ClO 2 ) 2……Page 206
7.3.2.3 Ba(ClO 4 ) 2……Page 207
7.3.4.4 Ca(ClO4)2……Page 208
7.3.5.3 CsClO4……Page 209
7.3.7.3 Cu(ClO4)2……Page 210
7.3.10.1 LiClO……Page 211
7.3.10.4 LiClO4……Page 212
7.3.11.3 Mg(ClO4)2……Page 213
7.3.14.2 Ni(ClO4)2……Page 214
7.3.15.2 KClO3……Page 215
7.3.15.3 KClO4……Page 216
7.3.16.3 Perchlorates……Page 217
7.3.17.3 RbClO4……Page 218
7.3.19.2 AgClO3……Page 219
7.3.20.2 NaClO3……Page 220
7.3.20.3 NaClO4……Page 221
7.3.22.2 TlClO3……Page 222
7.3.26.1 Zn(ClO3)2……Page 223
7.3.26.2 Zn(ClO4)2……Page 224
REFERENCES……Page 232
8.2.2 B ROMATES……Page 235
8.3.1.2 Ba(BrO 3 ) 2……Page 238
8.3.3.2 Ca(BrO4)2……Page 239
8.3.7.1 LiBrO2……Page 240
8.3.9.1 HgBrO3……Page 241
8.3.12.1 Bromates……Page 242
8.3.15.1 NaBrO3……Page 243
8.3.17.1 TlBrO3……Page 244
8.3.18 ZINC……Page 245
REFERENCES……Page 248
9.2.2 I ODATES……Page 250
9.2.3 P ERIODATES……Page 253
9.3.3 B ISMUTH……Page 254
9.3.5.1 Ca(IO3)2, Ca5(IO6)2……Page 255
9.3.6.2 CsIO4……Page 256
9.3.11.1 Fe(IO3)3……Page 257
9.3.13.1 LiIO3……Page 258
9.3.14.3 Mg2I2O9……Page 259
9.3.16.5 Hg4I2O9……Page 260
9.3.19.1 KIO3……Page 261
9.3.20.1 Ra(IO3)2……Page 262
9.3.22.1 RbIO3……Page 263
9.3.23.4 Ag5IO6……Page 264
9.3.24.4 NaIO4……Page 265
9.3.26.1 Tl(IO3)3……Page 266
9.3.30.1 Zn(IO3)2……Page 267
9.3.31.1 Zr(IO3)4……Page 268
REFERENCES……Page 276