Organic reactions

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Edition: 1

Volume: volume 5

ISBN: 0471395684, 9780471395683

Size: 23 MB (24447765 bytes)

Pages: 428/428

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Larry E. Overman0471395684, 9780471395683

Organic Reactions is a comprehensive series of volumes devoted to important synthetic reactions. For each volume, the authors are world-renowned experts with extensive hands-on experience in the field. The subjects are presented from the preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction, as well as tables listing all the pertinent examples of the reaction. The topics discussed in Volume 56 are the Hydroformylation reaction and the Vilsmeier reactions of non-aromatic compounds. Each reaction is presented with information about the reaction conditions, products, and yields where available, and is fully referenced to the primary literature.

Table of contents :
Cover Page……Page 1
ISBN 978-0471395683……Page 2
Table of Contents (with page links)……Page 3
CONTENTS (with page links)……Page 4
INTRODUCTION……Page 5
MECHANISM……Page 7
SCOPE AND LIMITATIONS……Page 16
COMPARISON WITH OTHER METHODS……Page 30
EXPERIMENTAL CONDITIONS……Page 37
EXPERIMENTAL PROCEDURES……Page 38
TABULAR SURVEY……Page 43
Table I. Hydroformylation of Unfunctionalized Alkenes……Page 49
Table II. Hydroformylation of Dienes and Polyenes……Page 95
Table III. Hydroformylation of Unsaturated Alcohols……Page 102
Table IV. Hydroformylation of Unsaturated Aldehydes and Ketones……Page 107
Table V. Hydroformylation of Unsaturated Esters……Page 108
Table VI. Hydroformylation of Unsaturated Ethers and Acetals……Page 117
Table VII. Hydroformylation of Unsaturated Halogen Compounds……Page 125
Table VIII. Hydroformylation of Unsaturated Nitrogen Compounds……Page 127
Table IX. Hydroformylation of Other Functionalized Alkenes……Page 139
Table X. Asymmetric Hydroformylation……Page 148
Table XI. Hydroformylation of Alkynes……Page 192
REFERENCES……Page 195
CONTENTS (with page links)……Page 218
INTRODUCTION……Page 219
SCOPE AND LIMITATIONS……Page 220
EXPERIMENTAL CONDITIONS……Page 265
EXPERIMENTAL PROCEDURES……Page 266
TABULAR SURVEY……Page 270
Table I. Alkenes……Page 271
Table II. Dienes, Trienes, and Tetraenes with Carbon Substituents……Page 280
Table III. Alkenes with Nitrogen Substituents……Page 287
Table IV. Dienes, Trienes, and Tetraenes with Nitrogen Substituents……Page 296
Table V. Alkenes with Oxygen Substituents……Page 299
Table VI. Dienes with Oxygen Substituents……Page 303
Table VII. Alkenes, Dienes, and Trienes with Sulfur Substituents……Page 307
Table VIII. Acetals, Ketals, and their Thio Analogs……Page 308
Table IX. Alkynes……Page 315
Table X. Aldehydes……Page 317
Table XI. Ketones……Page 319
Table XII. Imines, Hydrazones, Semicarbazones, and Oximes……Page 348
Table XIII. Carboxylic Acids, Anhydrides, and Acid Chlorides……Page 354
Table XIV. Esters and Lactones……Page 362
Table XV. Amides and Lactams……Page 364
Table XVI. Imides……Page 375
Table XVII. Nitriles……Page 376
Table XVIIIA. Methyl and Methylene Group: Activated by a Fully Conjugated Monocyclic Ring……Page 383
Table XVIIIB. Methyl and Methylene Groups Activated by a Fully Conjugated Polycyclic Ring……Page 392
REFERENCES……Page 401
CUMULATIVE CHAPTER TITLES BY VOLUME……Page 416

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