Characterization of Porous Solids VIIProceedings of the 7th International Symposium on the Characterization of Porous Solids (COPS-VII), Aix-en-Provence, France, 26-28 May 2005

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Series: Studies in Surface Science and Catalysis 160

ISBN: 0444520228, 978-0-444-52022-7, 0444520228

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P.L. Llewellyn, F. Rodriquez-Reinoso, J. Rouqerol and N. Seaton (Eds.)0444520228, 978-0-444-52022-7, 0444520228

The 7th International Symposium on the Characterization of Porous Solids (COPS-VII) was held in the Congress Centre in Aix-en-Provence between the 25th-28th May 2005. The symposium covered recent results of fundamental and applied research on the characterization of porous solids. Papers relating to characterization methods such as gas adsorption and liquid porosimetry, X-ray techniques and microscopic measurements as well as the corresponding molecular modelling methods were given. These characterization methods were shown to be applied to all types of porous solids such as clays, carbons, ordered mesoporous materials, porous glasses, oxides, zeolites and metal organic frameworks.

Table of contents :
Content:
Foreword
Pages v-vi
P.L. Llewellyn

Effect of pore morphology and topology on capillary condensation in nanopores: a theoretical and molecular simulation study Original Research Article
Pages 1-8
R.J.-M. Pellenq, B. Coasne, R.O. Denoyel, J. Puibasset

Density functional theory model of adsorption on amorphous and microporous solids Original Research Article
Pages 9-16
Peter I. Ravikovitch, Alexander V. Neimark

Thickness of adsorbed nitrogen films in SBA-15 silica from small-angle neutron diffraction Original Research Article
Pages 17-24
A. Schreiber, I. Ketelsen, G.H. Findenegg, E. Hoinkis

Strong light scattering upon capillary condensation in silica aerogels Original Research Article
Pages 25-32
G. Reichenauer, J. Manara, H. Weinläder

Characterisation of porous solids from nanometer to micrometer range by capillary condensation Original Research Article
Pages 33-40
R. Denoyel, M. Barrande, I. Beurroies

Characterization of zeolite membrane quality by using permporosimtrey Original Research Article
Pages 41-48
Kazuyuki Nakai, Kaori Nakamura, Jun Kaneshiro, Masahiko Matukata

Is the BET equation applicable to microporous adsorbents? Original Research Article
Pages 49-56
J. Rouquerol, P. Llewellyn, F. Rouquerol

A new classification of pore sizes Original Research Article
Pages 57-62
T.J. Mays

Characterization of nanoporous carbons Original Research Article
Pages 63-70
T.X. Nguyen, S.K. Bhatia

Adsorption and neutron scattering studies: a reliable way to characterize both the mesoporous MCM-41 and the filling mode of the adsorbed species Original Research Article
Pages 71-78
N. Floquet, J.P. Coulomb, P.L. Llewellyn, G. André, R. Kahn

Absolute assessment of adsorption-based microporous solid characterisation methods Original Research Article
Pages 79-86
M.J. Biggs, A. Buts, Q. Cai, N.A. Seaton

Molecular modeling of mercury porosimetry Original Research Article
Pages 87-94
F. Porcheron, P.A. Monson, M. Thommes

Predicting ambient temperature adsorption of gases in active carbons Original Research Article
Pages 95-103
M.B. Sweatman, N. Quirke, P. Pullumbi

Characterisation of periodic mesoporous silicas using molecular simulation Original Research Article
Pages 105-112
M. Pérez-Mendoza, C. Schumacher, N.A. Seaton

Structural characterization of porous carbonaceous materials using high-pressure adsorption measurements Original Research Article
Pages 113-120
Y. Belmabkhout, M. Frère, G. De Weireld

Microcalorimetric characterization of hydrogen adsorption on nanoporous carbon materials Original Research Article
Pages 121-128
Akihiko Matsumoto, Kazumasa Yamamoto, Tomoyuki Miyata

Effect of thermal treatments on the surface chemistry of oxidized activated carbons Original Research Article
Pages 129-136
J. Ruiz-Martínez, E.V. Ramos-Fernández, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso

Digital reconstruction of silica gels based on small angle neutron scattering data Original Research Article
Pages 137-144
J.D.F. Ramsay, M. Kainourgiakis, Th.A. Steriotis, A.K. Stubos

The impact of mesoporosity on microporosity assessment by CO2 adsorption, revisited Original Research Article
Pages 145-152
S. Brouwer, J.C. Groen, L.A.A. Peffer

A Monte Carlo study of capillary condensation of krypton within realistic models of templated mesoporous silica materials Original Research Article
Pages 153-160
Francisco R. Hung, Benoit Coasne, Keith E. Gubbins, Flor R. Siperstein, Matthias Thommes, Malgorzata Sliwinska-Bartkowiak

Using molecular simulation to characterise metal-organic frameworks and judge their performance as adsorbents Original Research Article
Pages 161-168
Tina Düren, Randall Q. Snurr

Stability of porous carbon structures obtained from reverse monte carlo using tight binding and bond order hamiltonians Original Research Article
Pages 169-176
S.K. Jain, J. Fuhr, R.J-M Pellenq, J.P. Pikunic, C. Bichara, K.E. Gubbins

Simulation of mercury porosimetry using MRI images of porous media Original Research Article
Pages 177-184
Matthew J. Watt-Smith, Sean P. Rigby, J.A. Chudek, Robin S. Fletcher

Adsorption and microcalorimetric measurements on activated carbons prepared from polyethylene terephtalate Original Research Article
Pages 185-192
M.C. Almazán-Almazán, M. Domingo-Carcía, I. Fernández-Morales, F.J. López-Garzon, I. Rodríguez-Ramos, A. Guerrero-Ruiz, A. Martínez-Alonso

Compressing some sol-gel materials and reduces their stiffness: a textural analysis Original Research Article
Pages 193-200
C.J. Gommes, N. Job, S. Blacher, J.-P. Pirard

Characterisation of new Pd/hierarchical macro-mesoporous ZrO2, TiO2, and ZrO2-TiO2 catalysts for toluene total oxidation Original Research Article
Pages 201-208
H.L. Tidahy, S. Siffert, J.-F. Lamonier, E.A. Zhilinskaya, A. Aboukaïs, Z.Y. Yuan, A. Vantomme, B.-L. Su, X. Canet, G. Deweireld, M. Frère

Characterisation of palladium supported on exchanged BEA and FAU zeolites for VOCs catalytic oxidation Original Research Article
Pages 209-216
H.L. Tidahy, S. Siffert, J.-F. Lamonier, E.A. Zhilinskaya, A. Aboukaïs, B.-L. Su, X. Canet, G. Deweireld, M. Frère, J-M Gireaudon, G. Leclercq

Comparison of transport characteristics and textural properties of porous material; the role of pore sizes and their distributions Original Research Article
Pages 217-224
Vladimír Hejtmánek, Petr Schneider, Karel Soukup, Olga àolcová

Effect of noble metal deposition in zeolitic structures on their adsorption capacities Original Research Article
Pages 225-232
X. Canet, J. Nokerman, M. Frère, H.L. Tidahy, S. Siffert, B.-L. Su

Influence of the Bentonite/Titania ratio on the textural characteristics of incorporated ceramics for photocatalytic destruction of volatile organic compounds Original Research Article
Pages 233-240
M. Yates, J.C. Martin, P. Ávila, F.J. Gil-Llambias

Simultaneous determination of intrinsic adsorption and diffusion of n-butane in activated carbons by using the TAP reactor Original Research Article
Pages 241-247
V. Fierro, Y. Schuurman, C. Mirodatos

Porous carbon deposits in controlled fusion reactor: adsorption properties and structural characterization Original Research Article
Pages 249-256
C. Martin, M. Richou, C. Brosset, W. Sakaily, B. Pégourié, P. Roubin

Characterization of the porosity of a microporous model carbon Original Research Article
Pages 257-264
Q. Cai, A. Buts, N.A. Seaton, M.J. Biggs

Qualitative assessment of the purity of multi-walled carbon nanotube samples using krypton adsorption Original Research Article
Pages 265-271
C.J. Gommes, F. Noville, C. Bossuot, J.-P. Pirard

Study of the anomalous behaviour of MFI zeolites towards nitrogen adsorption Original Research Article
Pages 273-278
Elpiniki Panayi, Charis R. Theocharis

Characterization of alkaline post-treated ZSM-5 zeolites by low temperature nitrogen adsorption Original Research Article
Pages 279-286
Yousheng Tao, Hirofumi Kanoh, Johan C. Groen, Katsumi Kaneko

Kureha activated carbon characterized by the adsorption of light hydrocarbons Original Research Article
Pages 287-294
W. Zhu, J.C. Groen, A. van Miltenburg, F. Kapteijn, J.A. Moulijn

Water adsorption/desorption isotherms for characterization of microporosity in sandstone and carbonate rocks Original Research Article
Pages 295-302
H. Fischer, N.R. Morrow, G. Mason

Determination of pore-size distributions of highly-connected networks with assisted-filling characteristics Original Research Article
Pages 303-310
Fernando Rojas, Carlos Felipe, Isaac Kornhauser, Salomón Cordero

Large-scale simulations of poly(propylene oxide)amine/Na+-montmorillonite and poly(propylene oxide) ammonium/Na+-montmorillonite using a molecular dynamics approach Original Research Article
Pages 311-318
P. Boulet, H.C. Greenwell, B. Chen, A.A. Bowden, I. Beurroies, F. Salles, P.V. Coveney, J.R.G. Evans, A. Whiting

A comparison of characterization methods based on N2 and CO2 adsorption for the assessment of the pore size distribution of carbons Original Research Article
Pages 319-326
C.O. Ania, J.B. Parra, F. Rubiera, A. Arenillas, J.J. Pis

Adsorption of nitrogen, hydrogen and carbon dioxide on alumina-pillared clays Original Research Article
Pages 327-334
A. Gil, R. Trujillano, M.A. Vicente, S.A. Korili

CH4 adsorption in Faujasite systems: Microcalorimetry and Grand Canonical Monte Carlo simulations Original Research Article
Pages 335-342
G. Maurin, P.L. Llewellyn, R.G. Bell

Amino-functionalized low density silica xerogels seen by different characterization methods Original Research Article
Pages 343-350
J. Mrowiec-Bialoń

CO2 adsorption in synthetic hard carbons Original Research Article
Pages 351-356
G. Reichenauer

Characterisation of nanoporous aluminosilicate monoliths derivatised with metal cations for selective propene-propane adsorption Original Research Article
Pages 357-364
M. Kargol, J. Zajac, D.J. Jones, J. Rozière, A.B. Jarzbski

Comparison of nitrogen and carbon dioxide as molecular probes of low surface area carbonaceous materials Original Research Article
Pages 365-374
M. Schneemilch, L. Bellarosa, K. Nakai, N. Quirke

Water sorption in hydrophobic porous materials: isotherm shapes and their meanings for the mesoporous MCM-41 and the microporous AIPO4-5 Original Research Article
Pages 375-382
N. Floquet, J.P. Coulomb, G. André, R. Kahn

Uncertainty in αs analyses and pore volumes propagated from uncertainty in gas adsorption data Original Research Article
Pages 383-388
A. Badalyan, P. Pendleton

Uncertainty in amount adsorbed and surface excess from uncertainty in high-pressure gas adsorption data Original Research Article
Pages 389-396
P. Pendleton

A new methodology to characterize the porosity of Y zeolites by liquid chromatography Original Research Article
Pages 397-406
L. Teyssier, E. Guillon, M. Thomas

Study of the microporous texture of active carbons by Small Angle Neutron Scattering Original Research Article
Pages 407-413
N. Cohaut, J.M. Guet, O. Manfroi, A. Albiniak, G. Furdin

Characterisation of nanostructured materials by combination of neutron scattering and 3D stochastic reconstruction techniques Original Research Article
Pages 415-422
E.S. Kikkinides, K.L. Stefanopoulos, Th.A. Steriotis, A.Ch. Mitropoulos, N.K. Kanellopoulos

Hydrogen storage in nanoporous carbons Original Research Article
Pages 423-430
O.Y. Odunsi, Y. He, T.J. Mays

Migration of siloxane polymer in ordered mesoporous MCM-41 silica channels Original Research Article
Pages 431-437
J. Goworek, A. Borówka, R. Zaleski

The sorption dynamics of propane, i-butane and neopentane in carbon nanotubes Original Research Article
Pages 439-446
J. Valyon, Zs. Ötvös, Gy. Onyestyák, L.V.C. Rees

Adsorption and diffusion kinetics of alkanes (C3&C5) on different CaA adsorbents Original Research Article
Pages 447-453
F. Benaliouche, M. Fodil Cherif, S. Belkhiri, Y. Boucheffa

Transport properties of catalyst supports derived from a catalytic test reaction Original Research Article
Pages 455-462
D. Enke, F. Friedel, T. Hahn, F. Janowski

Ellipsometric study of porosity distribution in hybrid silica-based sol-gel films Original Research Article
Pages 463-469
L. Wiŀaw-Solny, A. Kudŀa, J. Mrowiec-Biaŀoń, A.B. Jarzbski

Positronium annihilation study of as-synthesized MCM-41 silica under pressure Original Research Article
Pages 471-478
R. Zaleski, J. Goworek, A. Borówka

Structure-adsorptive characteristics of template-based mesoporous silicas containing residues of some phosphorus acids derivatives in their surface layer Original Research Article
Pages 479-486
O.A. Dudarko, I.V. Melnyk, Yu.L. Zub, A. Dbrowski

Melting of atomic layers in carbon nanotubes Original Research Article
Pages 487-494
Lucyna Firlej, Bogdan Kuchta

Molecular simulation study on the structure of templated porous materials obtained from different inorganic precursors Original Research Article
Pages 495-502
A. Patti, A.D. Mackie, F.R. Siperstein

The structure of high-pressure adsorbed fluids in slit-pores Original Research Article
Pages 503-509
Suresh K. Bhatia, Thanh X. Nguyen, Kien Tran, David Nicholson

Monte Carlo simulation of the isosteric heats—implications for the characterisation of porous materials Original Research Article
Pages 511-518
Yufeng He, Nigel A. Seaton

Pore size distribution in microporous carbons obtained from molecular modeling and density functional theory Original Research Article
Pages 519-526
Vanessa Fierro, Gemma Bosch, Flor R. Siperstein

Modeling triblock surfactant templated mesoporous silicas (MCF and SBA-15): A mimetic simulation study Original Research Article
Pages 527-534
Supryio Bhattacharya, Benoit Coasne, Francisco R. Hung, Keith E. Gubbins

Influence of temperature on water adsorption/desorption hysteresis loop in disordered mesoporous silica glass by Grand canonical Monte Carlo simulation method Original Research Article
Pages 535-541
Joël Puibasset, Roland J.-M. Pellenq

Determination of pore size distribution in microporous carbons based on CO2 and H2 sorption data Original Research Article
Pages 543-550
M. Konstantakou, S. Samios, Th.A. Steriotis, M. Kainourgiakis, G.K. Papadopoulos, E.S. Kikkinides, A.K. Stubos

Assessment of the development of the pore size distribution during carbon activation: a population balance approach Original Research Article
Pages 551-558
M.V. Navarro, N.A. Seaton, A.M. Mastral, R. Murillo

Chemically modified nanoporous carbons obtained using template carbonization method Original Research Article
Pages 559-566
C.O. Ania, T.J. Bandosz

Influence of the synthesis conditions on the pore structure and stability of MCM-41 materials containing aluminium or titanium Original Research Article
Pages 567-574
M.M.L. Ribeiro Carrott, C. Galacho, F.L. Conceição, P.J.M. Carrott

Effect of oxidizing agent on activated carbon cloth porosity and surface chemistry Original Research Article
Pages 575-582
P. Pendleton, A. Badalyan, R. Bromball, W. Skinner

Study of the efficiency of monolithic activated carbon adsorption units Original Research Article
Pages 583-590
M. Yates, J.A. Martin, M.A. Martin-Luengo, J. Blanco

Amino functionalisation of microemulsion templated mesoporous silica foams Original Research Article
Pages 591-598
S. Boskovic, F. Separovic, T.W. Turney, G.W. Stevens, M.L. Gee, A.J. O’Connor

Effect of activation process on resin based activated carbons Original Research Article
Pages 599-606
F.K. Katsaros, Th.A. Steriotis, A.K. Stubos, N.K. Kanellopoulos, S.R. Tennison

Highly microporous carbons prepared by activation of kraft lignin with KOH Original Research Article
Pages 607-614
V. Fierro, V. Torné-Fernández, A. Celzard

Preparation and characterization of nanoporous ternary mixed cerium oxides Original Research Article
Pages 615-620
Christothea Attipa, Charis R. Theocharis

Preparation and dynamic adsorption properties of activated carbons with tailored micro- and mesoporosity Original Research Article
Pages 621-628
P.A. Barnes, E.A. Dawson, M.W. Smith, J.L. Ward, H.M. Williams

Preparation of functionally graded alumina ceramic materials with controlled porosity Original Research Article
Pages 629-637
J. Andertová, J. Havrda, R. Tláskal

Preparation of mesoporous ceria in the presence of non-aqueous phases Original Research Article
Pages 639-644
Aphrodite Tillirou, Charis R. Theocharis

Preparation and characterization of nanoporous solids with composition CexMn1−xO2−y with x values 0 to 1 Original Research Article
Pages 645-650
Evroulla Hapeshi, Charis R. Theocharis

Thermal stability of ion exchange and adsorption properties of titania gels prepared from titanous chloride and hydrogen peroxide Original Research Article
Pages 651-660
A.R. Ramadan, N. Yacoub, J. Ragai

In-situ SAXS on transformations of mesoporous and nanostructured solids Original Research Article
Pages 661-665
Peter Laggner, Marlene Strobl, Philipp Jocham, Peter M. Abuja, Manfred Kriechbaum

Confinement effects on freezing of binary mixtures Original Research Article
Pages 667-674
Benoit Coasne, Joanna Czwartos, Keith E. Gubbins, Francisco R. Hung, Malgorzata Sliwinska-Bartkowiak

New equipment for characterization of nanofiltration membranes Original Research Article
Pages 675-680
V. Milisic, M. Mietton-Peuchot, T. Courtois

The porous structure of biodegradable scaffolds obtained with supercritical CO2 as foaming agent Original Research Article
Pages 681-688
S. Blacher, C. Calberg, G. Kerckhofs, A. Léonard, M. Wevers, R. Jérôme, J.-P. Pirard

Detection of specific electronic interactions at the interface aromatic hydrocarbon-graphite by immersion calorimetry Original Research Article
Pages 689-696
B. Bachiller-Baeza, A. Guerrero-Ruiz, I. Rodríguez-Ramos

Characterization and modelling of argillaceous porous medium by compressional and shear acoustic waves Original Research Article
Pages 697-704
J. Riffaud, A. Cerepi, J. Marrauld

Modelisation and circulation of fluids in geological porous systems. Images analyzing and mercury porosimetry Original Research Article
Pages 705-712
S. Galaup, R. Burlot, A. Cerepi, L. Wang, M. Dai

Electrical behaviour of saturated and unsaturated geological carbonate porous systems Original Research Article
Pages 713-719
A. Cerepi, C. Loisy, R. Toullec, R. Burlot, S. Galaup, M. Schmutz

Author index
Pages 721-724

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