Modern Aspects of Electrochemistry №16

Brian E. Conway, Ralph E. White, John O’M. Bockris9780306420245, 0-306-42024-4

Integrating both theoretical and applied aspects of electrochemistry, this acclaimed monograph series presents a review of the latest advances in the field. The current volume covers ion and electron transfer across monolayers of organic surfactants, determination of current distributions governed by Laplace’s equation, and three other subjects.

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Table of contents :
Preface……Page 4
Contents……Page 7
I. INTRODUCTION……Page 14
II. HISTORICAL……Page 16
III. STRUCTURE OF METALS……Page 17
IV. PREPARATION OF SINGLE-CRYSTAL-FACE ELECTRODES……Page 41
V. ELECTROCHEMICAL RESULTS……Page 56
REFERENCES……Page 111
I. INTRODUCTION……Page 115
II. ORIGIN OF POTENTIAL DEPENDENCE OF ELECTROCHEMICAL REACTION RATES……Page 119
III. THE EXPERIMENTAL SITUATION REGARDING THE TEMPERATURE DEPENDENCE OF TAFEL SLOPES……Page 128
IV. THEORETICAL DISCUSSION……Page 144
V. PROBLEMS WITH EVALUATION OF HEATS OF ACTIVATION WHEN a IS TEMPERATURE DEPENDENT……Page 180
VI CONCLUSIONS AND FINAL REMARKS……Page 194
REFERENCES……Page 197
I. INTRODUCTION……Page 201
II. CHARACTERISTIC ENERGY LEVELS IN THE ELECTRODE/ELECTROLYTE SOLUTION SYSTEM……Page 202
III. SPECIFIC FEATURES OF THE STRUCTURE OF THE SEMICONDUCTOR/ELECTROLYTE INTERFACE……Page 213
IV. QUASITHERMODYNAMIC APPROACH TO THE DESCRIPTION OF PHOTOELECTROCHEMICAL PROCESSES……Page 228
V. NEW APPLICATIONS……Page 248
VI. CONCLUDING REMARKS……Page 257
REFERENCES……Page 259
I. INTRODUCTION……Page 264
II. SERS EXPERIMENTAL STUDIES……Page 266
III. THEORETICAL MODELS OF SERS……Page 333
IV. WHAT IS “THE” SERS MECHANISM?……Page 359
V. SERS—A USEFUL TOOL……Page 361
REFERENCES……Page 368
I. INTRODUCTION……Page 381
II. EV BATTERY REQUIREMENTS……Page 383
III. CHARACTERISTICS OF INDIVIDUAL SYSTEMS……Page 401
IV. COMPARATIVE EV BATTERY CHARACTERISTICS……Page 433
REFERENCES……Page 437
I. INTRODUCTION……Page 446
II. MICROSTRUCTURE……Page 450
III. ION AND WATER DIFFUSION……Page 468
IV. TRANSPORT PROPERTIES UNDER INDUSTRIAL ELECTROLYSIS CONDITIONS……Page 479
V. CONDUCTIVITY AND PERMEABILITY IN MEMBRANES……Page 488
VI. CONCLUSION……Page 505
REFERENCES……Page 506
Index……Page 514