Spillover and Mobility of Species on Solid Surfaces

A. Guerrero-Ruiz and I. Rodriguez-Ramos (Eds.)9780444504272, 0444504273

“Spillover and Mobility of Species and Solid Surfaces” collects the papers which were presented at the Fifth International Conference Spillover, either as oral or poster contributions, as well as the summaries of the invited lectures. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, 1983, and continued in Leipzig, 1989, Kyoto 1993 and Dalian, 1997. For the fifth conference, held in S.L. el Escorial (Madrid), the organising committee has attempted to compile representative contributions which illustrate the advances in understanding the spillover phenomenon since 1997. Spillover is a process taking place during the interface of gas reactant molecules (mainly hydrogen and oxygen) on solid surfaces. However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc., have also been included. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.

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Table of contents :
Content:
Preface
Page v
A. Guerrero-Ruiz, I. Rodríguez-Ramos

Honorary scientific committee
Page xiii

International Advisory Board
Page xiii

National Advisory Board
Pages xiii-xiv

Organizing committee
Page xiv

Sponsoring
Page xiv

Hydrogenation by spillover of hydrogen from metal to acidic support or by reverse spillover of the reactant molecule from the support to the metal
Pages 1-2
R. Prins

Molecular hydrogen-originated protonic acid site Original Research Article
Pages 3-12
Hideshi Hattori

Spillover phenomena in stationary and non stationary hydrogen and syngas generation processes Original Research Article
Pages 13-30
P. Denton, E. Odier, C. Mirodatos

Involvement of support hydrogen in the H2-D2 isotopic exchange on sulfide catalysts Original Research Article
Pages 31-38
A. Scaffidi, L. Vivier, A. Travert, F. Maugé, S. Kasztelan, C. Scott, G. Pérot

In-situ FTIR study of hydrogen spillover and reaction kinetics in hybrid catalysts Original Research Article
Pages 39-46
Azfar Hassan, Kaoru Fujimoto, Keiichi Tomishige, Toshiaki Kusakari, Asuka Akasaka

H2 Adsorption in Rhodium metal catalysts supported in oxides with different reducibility Original Research Article
Pages 47-54
C. Force, J.P. Belzunegu, J. Sanz

Hydrogen spillover on a carbon supported platinum fuel cell catalyst: a computational and inelastic neutron scattering study Original Research Article
Pages 55-60
A.J. Ramirez-Cuesta, P.C.H. Mitchell, S.F. Parker, J. Tomkinson, D. Thompsett

TPR study of PdO catalysts supported on CexTi1−xO2 and CexY1−xO1.5+0.5x: effects of hydrogen spillover Original Research Article
Pages 61-68
Mengfei Luo, Wenjuan Shan, Pinliang Ying, Jiqing Lu, Can Li

Comparison of hydrogen spillover effect between cumene cracking and n-pentane hydroisomerization over Pt/SiO2+H-Beta using pulse reaction method Original Research Article
Pages 69-76
Toshiaki Kusakari, Keiichi Tomishige, Kaoru Fujimoto

FTIR evidences of the reactivity of spilt-over stored hydrogen: Transformation of Lewis acid sites into Brönsted sites on Pt/ZrO2 catalyst Original Research Article
Pages 77-84
Ruth L. Martins, Mariana M.V.M. Souza, Donato A.G. Aranda, Martin Schmal

Hydrogen spillover in H2 oxidation on Pd-Ti3+/TiO2 Original Research Article
Pages 85-92
V.V. Gorodetskii, A.V. Matveev

Hydroisomerization of C6-C14 n-alkanes over hybrid catalysts Original Research Article
Pages 93-100
T.V. Vasina, O.V. Masloboishchikova, E.G. Khelkovskaya-Sergeeva, L.M. Kustov, J.I. Houzvicka

Hydrogen spillover on supported TiO2 films doped by platinum particles Original Research Article
Pages 101-108
D.V. Malevich, A.F. Masez, V.G. Matys, I.M. Zharskii

Future research on spillover Original Research Article
Pages 109-116
Bernard Delmon

Oxygen transfer in the partial oxidation of propene on multi-component oxidic catalysts. A Solid Electrolyt Potentiometry aided study Original Research Article
Pages 117-124
H.-G. Lintz, M. Köhler

Oxygen storage and oxygen mobility on ceria and ceria-zirconia supported noble metals Original Research Article
Pages 125-134
S. Bedrane, C. Descorme, D. Duprez

Surface mobility and redox properties: Study of Pt/CeO2-ZrO2 catalysts Original Research Article
Pages 135-144
Toshitaka Tanabe, Akihiko Suda, Claude Descorme, Daniel Duprez, Hirofumi Shinjoh, Masahiro Sugiura

A rational strategy to design performant multiphasic oxide catalysts based on the cooperation between phases via spillover oxygen: the Bi-V-Sb-O system Original Research Article
Pages 145-156
E.M. Gaigneaux, F. Englebert, P. Ruiz

Synergy in Sn-Mo-Ti-O catalysts in the dehydrogenation of isopropanol to acetone Original Research Article
Pages 157-164
S.R.G. Carrazán, M. Jiménez, C. Martín, V. Rives

On some catalytic reactions recently revisited by H2, O2 and NO spillover Original Research Article
Pages 165-172
G.M. Pajonk

Surface diffusion modelling: Transfer matrix approach Original Research Article
Pages 173-180
A.V. Myshlyavtsev

A simple model to describe electrochemical promotion of catalysis Original Research Article
Pages 181-188
Ian S. Metcalfe

Electronic processes in hydrogen spillover Original Research Article
Pages 189-196
Jean-Marie Herrmann

Spillover-modified catalysis: Experimental rules and mathematical modeling Original Research Article
Pages 197-204
C. Vayenas, S. Brosda

Spillover effect for the oxidation of H2S in the presence of ammonia and water Original Research Article
Pages 205-212
Dae-Won Park, Byung-Kook Park, Dae-Kwang Park, Hee-Chul Woo

Compensation effects in the liquid-phase regioselective hydrogenation of functionalized alkenes on supported rhodium catalysts Original Research Article
Pages 213-222
F.M. BauTista, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, A.A. Romero

NMR relaxation of chloroform adsorbed over alkali-exchanged FAU type zeolites Original Research Article
Pages 223-230
M. Sánchez-Sánchez, A. Vidal-Moya, T. Blasco

Simultaneous isomerization of n-heptane and hydrogenation of benzene over bimetallic PtMe/Beta catalysts in the absence and presence of sulfur Original Research Article
Pages 231-238
M.A. Arribas, V. Fornés, A. Martínez

CH4 and CO2 transformations initiated by hydrogen-accumulated systems. Role of spillover and lattice bound hydrogen Original Research Article
Pages 239-250
M.V. Tsodikov, V.Ya. Kugel, F.A. Yandieva, E.V. Slivinskii, I.I. Moiseev, G. Colón, M.C. Hidalgo, J.A. Navío

Effect of hydrogen spillover in hydrogenolysis and cracking of butane on Co-niobia-silica catalysts Original Research Article
Pages 251-258
F. Tiu, V. Pąrvulescu, P. Grange, V.I. Pąrvulescu

Effect of hydrogen spillover on toluene disproportionation and hydrogenation over HMOR-Pt/Al2O3 Original Research Article
Pages 259-266
Zhu Zhirong, Chen Qinglin, Yang Deqin, Chen Wencai, Yu Gaoqin

Study on reactions between H2 and NOx over noble metal-loaded NOx-adsorbing metal oxides Original Research Article
Pages 267-274
M. Machida, D. Kurogi, T. Kijima

Hydrogen spillover in Pt-Sn catalysts supported on activated carbon cloth Original Research Article
Pages 275-282
A. Huidobro, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso

Hydrogen spillover effect in the reduction of barium nitrate of RuBa(NO3)2/AC catalysts for ammonia synthesis Original Research Article
Pages 283-290
Changhai Liang, Zhaobin Wei, Mengfei Luo, Pinliang Ying, Qin Xin, Can Li

Hydrogen spillover measured by mass spectroscopy during reduction of carbon supported palladium catalysts: Effect of carbon properties Original Research Article
Pages 291-298
A.L.D. Ramos, D.A.G. Aranda, M. Schmal

Direct FTIR insight in the spillover hydrogen reactivity: CO and NO chemisorbed on Ru NaY zeolite Original Research Article
Pages 299-306
Ruth Leibsohn Martins, Maria Auxiliadora S. Baldanza, Marcos Teixeira Lima, Martin Schmal

Dual-function catalysts for ring opening of cyclic compounds Original Research Article
Pages 307-314
L.M. Kustov, A.Yu. Stakheev, T.V. Vasina, O.V. Masloboishchikova, E.G. Khelkovskaya-Sergeeva, P. Zeuthen

Synergy effect between copper and manganese oxides in hopcalite catalysts Original Research Article
Pages 315-322
F.C. Buciuman, F. Patcas, T. Hahn

Spillover of oxygen species in the catalysts for NO decomposition Original Research Article
Pages 323-330
V.I. Pârvulescu, B. Delmon, P. Grange

Effects of oxygen spillover on the catalytic oxidation of BTEX in air with Pt/CeO2 catalyst Original Research Article
Pages 331-338
Dong-Keun Lee, Dul-Sun Kim, Kee Chool Wang, Soo-Gon Kim

The role of Cu in the reactivity of Cu/ZrO2 catalysts for the SCR of NO with CH4 Original Research Article
Pages 339-346
A. Caballero, J.J. Morales, J.P. Holgado, J.P. Espinos, M. Ocaña, J.A. Anderson, A.R. González-Elipe

Oxygen handling properties of Ce-Ca mixed oxides solutions Original Research Article
Pages 347-354
A. Iglesias-Juez, A.B. Hungría, O. Gálvez, M. Fernández-García, A. Martínez-Arias, A. Guerrero-Ruiz, J.C. Conesa, J. Soria

On the surface interaction between atomic oxygen and carbon: electronic and morphology changes in a model carbon material as studied by scanning probe microscopies Original Research Article
Pages 355-362
J.I. Paredes, A. Martínez-Alonso, J.M.D. Tascón

Enhancement of the Catalytic Performance of NiMoO4 and Modification of the Kinetic parameters of Oxidative Dehydrogenation of Propane over NiMoO4/Sb2O4 Biphasic Catalyst by Oxygen spillover Original Research Article
Pages 363-370
H.M. AbdelDayem, P. Ruiz

Is spillover a key factor in SCR reaction over a physical mixture of V2O5 with TiO2-SO42−? Original Research Article
Pages 371-378
Seong Moon Jung, Paul Grange

Comparative determination of surface and lattice oxygen mobility on vanadium phosphorus oxides by isotopic exchange with C18O2 Original Research Article
Pages 379-386
B. Bachiller-Baeza, I. Rodríguez-Ramos, J.C. Volta, M. Cerro-Alarcón, A. Guerrero-Ruiz

The structures, catalytic properties and spillover effects of the catalysts Co-Pt(Pd, Rh)/Ce-Al−O Original Research Article
Pages 387-394
M. Meng, P.-Y. Lin, Y.-L. Fu, S.-M. Yu

Effects of ceria on propane reforming over alumina supported palladium catalysts Original Research Article
Pages 395-404
A.L. Guimarães, L.C. Dieguez, M. Schmal

Effect of ceria additive loading on Ni/SiO2 catalysts for carbon dioxide reforming of methane Original Research Article
Pages 405-412
K. Kouachi, S. Menad, S. Tazkrit, O. Cherifi

Chlorine mobility in Pt/Al2O3 and Pt/Al2O3/Al complete oxidation catalysts Original Research Article
Pages 413-420
M. Paulis, N. Burgos, C. López-Cartes, J.M. Gatica, J.J. Calvino, M. Montes

Migration of carbonaceous materials formed during wet oxidation of phenol with supported Pt catalysts Original Research Article
Pages 421-428
Dong-Keun Lee, Sang-Jun Ahn, Dul-Sun Kim

Possible role of spillover processes in the operation of NOx storage and reduction catalysts Original Research Article
Pages 429-436
Allan J. Paterson, Daniel J. Rosenberg, James A. Anderson

Alumina supported molybdenum-nickel carbides as catalysts for the dry reforming of methane Original Research Article
Pages 437-444
P. Ferreira-Aparicio, S. Menad, A. Guerrero-Ruiz, I. Rodríguez-Ramos

Selective hydrogenation of 1,3-butadiene on molybdenum nitride catalyst: Identification of the adsorbed hydrocarbonaceous species Original Research Article
Pages 445-452
Zili Wu, Zhixian Hao, Zhaobin Wei, Can Li, Qin Xin

Static purification-concentration process. Study of the system uranium, orthophosphoric acid-Di(ethyl-2-hexyl) phosphoric acid-Tri-n-octyl phosphine oxyde-Ammonium carbonate Original Research Article
Pages 453-460
F. Hassaine-Sadi, A. Benhassaine

Improvement on the dry reforming of methane by hydrogen diffusion in a membrane reactor Original Research Article
Pages 461-468
P. Ferreira-Aparicio, Y.H. Ma

Author index
Pages 469-471

Subject index
Pages 473-475