Physical Chemistry, Second Edition

Robert G. Mortimer9780125083454, 0125083459

Книга Physical Chemistry, Second Edition Physical Chemistry, Second EditionКниги Химия Автор: Robert G. Mortimer Год издания: 2000 Формат: pdf Издат.:Academic Press Страниц: 1128 Размер: 102,7 ISBN: 0125083459 Язык: Английский0 (голосов: 0) Оценка:ReviewPraise for the first edition: “[T]his text has all the necessary ingredients to be used for a two-semester undergraduate physical chemistry course…. Anyone teaching physical chemistry will want to have a copy of this book as a reference. Professors will find the figures and problems to be particularly useful.” –Journal of Chemical Education”Robert Mortimer’s book provides an in-depth and clear presentation of the subject. The chapter problems and examples are useful in giving students exercise in what they have read.” –David Lawson, University of Michigan-Dearborn”This text is my new favorite thermo/kinetics book. It presents both the concepts and relevant equations in a clear, understandable fashion and moves easily from basic or review concepts to more advanced topics.” –Cynthia M. Woodbridge, Hillsdale College”Mortimer’s Physical Chemistry textbook is well written, complete, and it will be easily read by students and instructors. The material covered is current and concise, and the in-chapter and end-of-chapter problems enhance the students’ learning experience. I recommend this book.” –Jason D. Hofstein, Siena College –This text refers to the Hardcover edition. Product DescriptionThis new edition of Robert G. Mortimer’s Physical Chemistry has been thoroughly revised for use in a full year course in modern physical chemistry. In this edition, Mortimer has included recent developments in the theories of chemical reaction kinetics and molecular quantum mechanics, as well as in the experimental study of extremely rapid chemical reactions. While Mortimer has made substantial improvements in the selection and updating of topics, he has retained the clarity of presentation, the integration of description and theory, and the level of rigor that made the first edition so successful.* Emphasizes clarity; every aspect of the first edition has been examined and revised as needed to make the principles and applications of physical chemistry as clear as possible. * Proceeds from fundamental principles or postulates and shows how the consequencesof these principles and postulates apply to the chemical and physical phenomena being studied.* Encourages the student not only to knowthe applications in physical chemistry but to understand where they come from.* Treats all topics relevant to undergraduate physical chemistry.

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Table of contents :
Contents……Page 2
Preface……Page 3
Acknowledgements……Page 5
Periodic Table of the Elements……Page 6
Information Tables……Page 7
1 – Systems, States, and Processes……Page 10
2 – The Equilibrium Macroscopic States of Gases and Liquids……Page 29
3 – Work, Heat, and Energy – The First Law of Thermodynamics……Page 53
4 – The Second and Third Laws of Thermodynamics – Entropy……Page 102
5 – The Thermodynamics of Real Systems……Page 137
6 – Phase Equilibrium……Page 173
7 – Multicomponent Systems……Page 205
8 – The Thermodynamics of Chemical Equilibrium……Page 261
9 – The Thermodynamics of Electrical Systems……Page 296
10 – Gas Kinetic Theory. The Molecular Theory of Dilute Gases at Equilibrium……Page 324
11 – Transport Processes……Page 370
12 – The Rates of Chemical Reactions……Page 406
13 – Chemical Reaction Mechanisms……Page 440
14 – The Principles of Quantum Mechanics. I. Classical Waves and the Schrodinger Equation……Page 498
15 – The Principles of Quantum Mechanics. II. The Postulates of Quantum Mechanics……Page 544
16 – The Electronic States of Atoms. I. The Hydrogen Atom and the Simple Orbital Approximation for Multielectron Atoms……Page 577
17 – The Electronic States of Atoms. II. Higher-Order Approximations for Multielectron Atoms……Page 623
18 – The Electronic States of Molecules……Page 650
19 – Translational, Rotational, and Vibrational States of Atoms and Molecules……Page 723
20 – Spectroscopy and Photochemistry……Page 752
22 – The Structure of Solids and Liquids……Page 817
23 – Some Additional Theories of Nonequilibrium Processes……Page 867
Appendix A – Tables of Numerical Data……Page 897
Appendix B – Some Useful Mathematics……Page 920
Appendix C – A Short Table of Integrals……Page 940
Appendix D – Classical Mechanics……Page 943
Appendix E – Some Derivations of Thermodynamic Formulas and Methods……Page 949
Appendix F – Some Mathematics in Quantum Mechanics……Page 954
Appendix G – The Perturbation Method……Page 961
Appendix H – The Huckel Method……Page 963
Appendix I – Matrix Representations of Groups……Page 967
Appendix J – Symbols Used in This Book……Page 976
Appendix K – Answers to Selected Exercises and Problems……Page 983
Additional Reading……Page 1010
Index……Page 1018