Organosilicon chemistry: from molecules to materials

n Auner3527290613, 9783527290611, 1560818697, 9781560818694

Organosilicon Chemistry at its best… Like its hugely successful predecessor, this volume presents the latest developments in a rapidly developing field of industrial and academic research. Written by leading experts, it is a unique handbook for every scientist concerned with organosilicon compounds and their applications. From reviews of the first volume: ‘The excellent presentation of its contents guarantees that it will occupy a prominent place within the literature on silicon chemistry.’ Nachr. Chem. Lab. Techn. ‘… I do recommend this book highly to those scientists in academia and industry who are active in molecular organosilicon chemistry and/or silicon-based materials science.’ Synthesis

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Table of contents :
Cover Page……Page 1
Title Page……Page 4
ISBN 3527290613……Page 5
PREFACE……Page 7
EDITORS’ PREFACE……Page 8
Contents (with page links)……Page 10
Tetravalent Organosilicon Compounds: Chemistry and Structure……Page 22
Structures of Small Silicon-Containing Compounds – Why and How?……Page 24
Sterically Overcrowded Organosilicon Compounds and their Properties……Page 32
Synthesis of Functional Substituted Oligosilanes Based on Silyltriflate Derivatives……Page 42
Electroreductive Formation of Di- and Polysilanes……Page 48
Linear Tetrasilanes with Internal Substituents: Qligosilanes with Optical Activity……Page 52
A New Way to Si-Ge and Si-Sn Bonds: Hexachlorodisilane Cleavage of Organometal Phosphanes……Page 56
29Si29Si-Coupling Constants of Bromo- and Iododisilanes and -trisilanes XnSi2H(6-n) and XnSi3H(8-n) (X = Br,I)……Page 58
Calculation of the 29Si NMR Chemical Shifts in Molecules with SiN, SiCl, and SiSi Bonds……Page 60
Reactivity of Very Electron-Rich Organosilyl Amines……Page 62
Lithiated Aminofluorosilanes as Precursors for Monomeric and Dimeric Iminosilanes……Page 64
Fluorofunctional Silylamines and -Hydrazines – Precursors of (Si-N) Ring Systems……Page 66
New Approaches to (Fluoromethy1)silanes……Page 70
Homo- and Heterocyclic Si-O-Systems-Rings and Cages……Page 72
Silaheterocycles from Intramolecular Reactions of Siliconfunctionalized Diazoacetic Esters……Page 78
Synthesis and Reaction Behavior of Organoalkoxysilylphenols……Page 82
N-Silylation: New Possibilities for Long-Known Amines……Page 86
On the Acid-catalyzed Reaction of Siloxanes with Alcohols……Page 88
On the Reactivity of Chlorosiloxanes……Page 90
Chlorosilanols – more stable than you think – shown with 29Si NMR……Page 92
Diorganosilyl-bis(O-alkylphosphonates)……Page 96
Subvalent and Unsaturated Organosilicon Compounds: Formation and Reactivity……Page 100
Basic Principles of the Theory of Bonding in Silicon Compounds……Page 102
Expectations from an Unusual Compound: The Chemistry of Decamethylsilicocene……Page 108
Cp*2Si(CO) and Cp*2Si(N2): Complexes of Decamethylsilicocene……Page 114
Silicon and Phosphinomethanides: A Novel Entry to Hypervalent and Low Valent Organosilicon Chemistry……Page 116
Neopentyilsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?……Page 124
Synthesis and Thermolysis Reactions of Si-functionalized 2-Silaazetidines……Page 136
Reactions of Silaethenes in the Gas Phase and in Solution……Page 140
The Reaction of Vinylsilanes with Lithium Metal……Page 144
Small Silicon Ring Compounds: Formation and Reactions……Page 146
Matrix Photolysis of Simple Azidosilanes……Page 152
Low-Coordinated Si-Compounds: Gas Phase Reactions with Heterosubstituted Silylenes……Page 160
Unusual Coordination in Phosphorus Silicon Compounds……Page 164
Unsaturated Silicon Compounds – Matrix IR Investigations and Quantum Chemical Calculations……Page 168
Hypervalent Organosilicon Compounds: Formation, Structure and Chemistry……Page 176
Reactivity of’ Penta- and Hexacoordinated Silicon Species……Page 178
Compounds with High Coordination Numbers at Silicon: Models for the Investigation of the Nucleophilic Substitution Reaction at Silicon Centers……Page 186
Organosilicon Metal Compounds: Coordination Chemistry and Catalysis……Page 188
A Silane-Induced CO-Activation and CC-Coupling Reaction: Modeling of Active Surface Sites……Page 190
Organometal Fragment Substituted Silanols, Siloxanes and Silylamines……Page 206
On the Complex Chemistry of Cyclopentadienyl Ligands with Oligoethylene Glycol Ether Tentacles……Page 214
Heterometalllic Complexes with a Bridging Alkoxy-Silyl Ligand: η2-μ2-Si( OR)3……Page 218
Silicon-Containing Main Group – Transition Metal Complexes……Page 220
Silicon-containing Bimetallics Fe-M( M = Ni, Pd, Pt) with M-Coordinated Organic Ligands……Page 222
Anionic Transition Metal Silyl Complexes: New Building Blocks in Coordination Chemistry……Page 226
Synthesis and Characterization of New Transition Metal-Silicon Compounds……Page 234
The Silicon Effect in Metallic Silylamides……Page 238
New Chemistry for Reactive Transition-Metal Silicon Bonds……Page 246
Organosilane Chemistry at Tailor-made Platinum Centers……Page 252
Silicon Polymers: Formation and Application……Page 272
Regioselectivity in Hydrosilylation Reactions……Page 274
Network Characterization of Photocross-linked Silicone Acrylates……Page 282
Photocross-linking of α,ω-Vinyl Terminated Silicones with Silicones Containing Pendant Mercapto Groups……Page 284
Investigations into the Relaxation Behavior of Polymer Siloxanes……Page 286
Dicyclopentadienyl Units Containing Silicone Surfactants……Page 288
Applications of Transition Metal Compounds in the Preparation of Useful Silicon-Containing Ceramics……Page 290
New Ways to Polysilanes – Starting Compounds for New Silicon Materials……Page 296
Anionic Polymerization of Masked Disilenes: Mechanism, Scope and Applications……Page 306
Ceramic Fibers from Organosilicon Polymers……Page 314
Novel Multifunctional (Meth)acrylate Alkoxysilanes as Precursors for Inorganic-Organic Copolymers……Page 322
Processing, Properties and Structural Development of Polymer-derived Fiber-reinforced SiC……Page 324
Metal/SiO2 Nanocomposites by Sol-Gel Processing……Page 340
Organically Modified SiO2 Aerogels……Page 344
Spectroscopic Investigations on Silylated Inorganic Substrates……Page 346
Materials for Optical Data Processing……Page 352
Thick Siloxane Films from Tetraethoxysilane on Silicon Wafers……Page 354
Chemical Relaxation of SiH4, Si2H6, SiH2, and H2 in Low Pressure Discharges……Page 358
Kinetic and Mass Spectroscopic Investigations of Plasma Induced Deposition of Silicion Dioxide from Tetraethylorthosilicate and Oxygen……Page 362
Author Index (with page links)……Page 364
Subject Index (with page links)……Page 366