Encyclopedia of Physical Science and Technology – Materials

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Robert A. Meyers (Editor-in-Chief)

Nine years has passed since the 1992 second edition of the encyclopedia was published. This completely revised third edition, which is a university and professional level compendium of chemistry, molecular biology, mathematics, and engineering, is refreshed with numerous articles about current research in these fields. For example, the new edition has an increased emphasis on information processing and biotechnology, reflecting the rapid growth of these areas. The continuing Editor-in-Chief, Robert Meyers, and the Board prepared a new topical outline of physical science and technology to define complete coverage. Section editors are either Nobel Laureates or editors of key journals in their fields. Additional Board members representing the global scientific community were also recruited.

Table of contents :
Glossary……Page 1
History of Adhesionand Adhesives……Page 2
Chemical……Page 3
Classification of Adhesives……Page 4
Polychloroprene Adhesives……Page 5
Epoxides……Page 6
Acrylates……Page 8
Phenolics……Page 9
Surface Preparation for Bonding……Page 10
Coupling Agents and Primers……Page 11
Test Methods……Page 12
References……Page 14
Glossary……Page 15
History of Aluminum……Page 16
Natural Occurrence of Aluminum Compounds……Page 17
Extraction of Pure Alumina……Page 18
Electrolytic Reduction of Alumina to Aluminum (Hall–H ´Eroult Process)……Page 21
Feeding and Tapping Cells……Page 22
Anode Effect……Page 23
Energy Considerations……Page 24
Alternative Processes for Producing Aluminum……Page 26
Production of Ultra-High-Purity Aluminum……Page 27
Inorganic Compounds……Page 28
Organic Compounds……Page 29
Effect of Alloying……Page 30
Corrosion Resistance……Page 31
Wrought Alloys……Page 32
Temper Designations……Page 34
Casting……Page 35
Uses of Aluminum……Page 36
References……Page 38
Glossary……Page 39
Raw Material for Carbon Fibers……Page 40
Oxidative Stabilization of PAN Fibers……Page 41
Shrinkage during Stabilization……Page 42
Chemistry of Oxidative Stabilization……Page 43
Post Spinning Modification……Page 44
Carbon Fibers from Pitch……Page 45
Spinning of Mesophase Pitch……Page 46
Carbon Fibers from Cellulose……Page 47
Carbon Fiber Structure……Page 48
Crystallite Orientation in Carbon Fibers……Page 49
Structural Models……Page 50
Duplex Model……Page 51
Surface Treatment of Carbon Fibers……Page 52
Young’s Modulus……Page 54
Carbon Fiber Demand-Pattern……Page 55
Further Agenda……Page 56
Applications of Carbon Fibers……Page 57
Aerospace Applications……Page 58
Adsorption……Page 60
References……Page 63
Glossary……Page 64
Ionic Conductors……Page 66
Ceramic Capacitors……Page 67
Dielectric Resonator……Page 68
PTC Thermistors……Page 69
NTC Thermistor……Page 71
Ceramic Varistor……Page 72
Introduction……Page 73
Pb(B B )O3-PbTiO3 Ceramic Materials……Page 74
Pb(B B )O3-PbTiO3 Single Crystals……Page 75
Application of New Pb(B B )O3-PbTiO3 Materials……Page 76
Piezoelectric Ceramics……Page 77
Applications of Piezoelectric Ceramics……Page 78
Low Firing Multilayer Ceramic Substrates……Page 83
Introduction……Page 84
Materials……Page 85
Fabrication Process……Page 86
Substrate Properties……Page 89
Applications……Page 90
MMC substrate applications……Page 91
Future Development……Page 92
Transmission Characteristics……Page 93
SrTiO3 Varistor……Page 94
Ceramics in Reciprocating Internal Combustion Engine……Page 95
Ceramics in Gas Turbine Engine……Page 96
Introduction……Page 97
MnZn-Ferrites……Page 99
NiCuZn-Ferrites……Page 100
Co-firing with Ag and ferrites……Page 101
Hard Ferrites……Page 104
Concluding Remarks……Page 108
Microstructure……Page 109
Ceramics for Biomedical Applications……Page 110
Calcium Phosphate Cements……Page 111
References……Page 112
Glossary……Page 115
Principles……Page 116
Ceramic Yield……Page 117
Precursor Synthesis……Page 118
Polysilazanes and Related Polymers……Page 119
Introduction of Other Elements: The Si–C–E–N(O) System……Page 120
Cross-linking and Pyrolysis……Page 121
Cross-Linking……Page 122
Degradation Stage……Page 123
Mineralization Stage……Page 125
Nitridation and Free-Carbon Removal Stages……Page 126
Fibers……Page 127
Binders and Sintering Aids……Page 128
Outlook……Page 129
References……Page 130
Glossary……Page 131
Natural Resins……Page 133
Air Drying of Oils……Page 134
Alkyds……Page 135
Acrylic Resins and Styrene……Page 136
Epoxy Resins……Page 137
Vinylidene Chloride-Containing Polymers……Page 138
Silicones……Page 139
Chromic oxides…….Page 140
Organic Pigments……Page 141
Solvents……Page 142
High Solids Coatings……Page 143
Waterborne Coatings……Page 144
References……Page 145
Glossary……Page 147
Characteristics……Page 148
Constituent Materials……Page 149
Properties of Composites……Page 151
Analysis of Composites……Page 153
Open-Mold Processes……Page 157
Closed-Mold Processes……Page 158
Uses of Composites……Page 159
References……Page 160
Glossary……Page 161
History……Page 162
Structure……Page 163
Formation……Page 164
Devitrification……Page 165
Silica……Page 166
Viscosity of Glass……Page 167
Annealing Process……Page 169
Coefficient of Thermal Expansion……Page 170
Thermal Conductivity……Page 173
Specific Heat……Page 174
Electrical Properties……Page 175
Dielectric Loss Factor……Page 176
Optical Properties……Page 177
Manufacture……Page 180
Lamp Glass……Page 181
Glass Fibers……Page 184
See also the Following Articles……Page 185
References……Page 186
Glossary……Page 187
Melting, Forming, and Ceramming……Page 188
Mechanical Properties……Page 189
Simple Silicates……Page 190
Sheet Fluorosilicate Glass-Ceramics……Page 191
Chain Fluorosilicate Glass-Ceramics……Page 192
β-Quartz Solid-Solution Glass-Ceramics……Page 193
β-Spodumene Solid-Solution Glass-Ceramics……Page 194
Phosphates……Page 195
References……Page 196
Glossary……Page 197
Fibers Resulting from a Solid or Liquid Precursor……Page 198
Vacuum Impregnation……Page 199
Semisolid-Phase Manufacturing Process: Compocasting……Page 200
Aluminum Matrix Composites……Page 202
Mechanical Properties……Page 203
Structure–Performance Maps……Page 204
References……Page 205
Glossary……Page 206
A, X, and Y Zeolite Structures……Page 207
Mordenite, ZSM-5, and ZSM-11 Structures……Page 208
Zeolite Synthesis……Page 209
Selective Ion Exchangers……Page 210
Catalysts……Page 211
Smectite Clays……Page 212
Aluminophosphates……Page 213
Metal Substituted AlPOs and SAPOs……Page 214
References……Page 215
Glossary……Page 216
Layered Hosts……Page 217
Preparing Nanocomposites……Page 219
In Situ Polymerization……Page 221
Direct Intercalation……Page 222
Thermal or Chemical Conversion……Page 223
Structures with Layered Inorganic Hosts……Page 224
Electronic/Electrochemical Properties……Page 226
Structural/Mechanical Properties……Page 227
Optical Properties……Page 228
References……Page 230
Glossary……Page 231
Basic Phosphor Theory……Page 232
Fluorescent Lamp Phosphors……Page 233
Halophosphate Phosphor……Page 234
CeMgAl11O19: Tb3+ (CAT)……Page 235
GdMgB5O10:Ce3+,Tb3+(CBT)……Page 236
Phosphors for High-Pressure Mercury Vapor Lamps……Page 237
Quantum-Splitting Phosphors (Qsps) And Mercury-Free Fluorescent Lamps……Page 238
Phosphors for Plasma Display Panels (Pdps)……Page 239
Scintillator Materials……Page 241
LaOBr:Tm3+……Page 242
Computed Tomography……Page 243
Nuclear Cameras and Positron Emission Tomography (Pet)……Page 244
Cathodoluminescent Phosphors and Color Television……Page 245
Phosphors for White Light-Emitting Diodes (Leds)……Page 246
References……Page 247
Introduction……Page 249
Mechanism of Darkening and Fading……Page 250
Formation of Photochromic Glasses……Page 252
Performance of Photochromic Glasses……Page 253
Benefits and Alleged Detriments……Page 255
Refenences……Page 256
Brief History……Page 257
Classifications……Page 258
Applications……Page 259
Mechanical Aspects……Page 260
Recent Developments……Page 261
References……Page 262
Introduction……Page 263
Molecular Structures……Page 264
Coupling a Polar Group to a Reactive Silicone……Page 266
Aqueous Surface Activity……Page 267
Aqueous Phase Behavior……Page 268
Polymeric Silicone Surfactants……Page 269
Wetting……Page 270
Inks, Paints, and Coatings……Page 271
Personal Care……Page 272
Supercritical CO2……Page 273
References……Page 274
Current U.S. Laws and Agencies……Page 275
Changing Requirements……Page 277
References……Page 280
Glossary……Page 281
Properties of Textile Fibers……Page 282
Yarn……Page 283
Blended and Composite Yarns……Page 285
Ropes……Page 286
Braids……Page 287
Woven fabric structures……Page 288
Weft knitting……Page 289
Nonwoven Structures……Page 290
Sizing and Weaving……Page 291
Textile Operations in the Future……Page 292
References……Page 293
Glossary……Page 294
Refining Techniques……Page 295
International Tin Agreements……Page 296
Tin Plate Manufacture……Page 297
Three-Piece Can Manufacture……Page 298
Solder……Page 299
Soldering Essentials……Page 300
Die-casting alloys……Page 301
Tin–Lead Alloy Electrodeposits……Page 302
Terneplate……Page 303
Organotin Stabilizers……Page 304
References……Page 305
Glossary……Page 307
Uses……Page 308
Production……Page 309
Types of Deposits……Page 310
Mining……Page 311
Nuclear Fuel……Page 312
References……Page 313

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