inorganic chemistry ticc–124

J.H. Holloway, C.K. Jorgensen, K. Schwochau, H. Selig3540135340, 9783540135340

Table of contents :
Contents……Page 5
The Problems for the Two-electron Bond in Inorganic Compounds; Analysis of the Coordination Number N……Page 6
1 Electricity, Electrons and Chemistry……Page 7
2 Oxidation States and the Periodic Table……Page 9
3 Coordination Number N from Werner to Bjerrum……Page 11
4 Crystallographic Def’mition of Bonds……Page 14
5 High N Values Without Available Electron-pairs……Page 16
6 Aqua Ions and Related Problems……Page 21
7 Special Extensions of the Lewis Paradigm:……Page 24
8 Can Quantum Chemistry Save the Situation?……Page 29
9 Kossel versus Lewis, Present Status……Page 32
10 References……Page 33
Cationic and Anionic Complexes of the Noble Gases……Page 37
A Introduction……Page 39
I [Xe2]+……Page 40
1 Introduction……Page 41
2 [ArF]+……Page 43
a Preparations and Structures……Page 44
b Oxidative Fluorinating Abilities……Page 49
a Adducts Incorporating Pentafluorides……Page 50
c Adducts Incorporating Oxide Tetrafluorides……Page 59
d Adducts Incorporating Fluorosulphate and Related Groups……Page 60
e FXeN(SO2F)2……Page 61
5 [Rn] ^2+, [RnF]+ and [Rn2F3]+……Page 62
2 Syntheses……Page 63
3 Structures……Page 64
4 Vibrational Spectroscopy……Page 66
1 Introduction……Page 67
a The Preparation and Nature of the Adducts……Page 68
b The structures of the Adducts in the Solid State and in Solution……Page 70
b The Structures of the Adducts in the Solid State and in Solution……Page 75
V [XeOF3]+……Page 76
VI [XeO2F]+……Page 78
VII [XeOF5]+……Page 79
VIII [XeOTeF5]+……Page 80
IX [(FXeO)2S(O)F]+……Page 82
I [XeF8]2- and [XeF7]-……Page 85
II [XeOF5]- and [Xe3O3F13]-……Page 86
III [XeO3X]- (X = F, CI, Br)……Page 88
IV [XeOF3]- and [XeO2F3]-……Page 90
D References……Page 91
Extraction of Metals from Sea Water……Page 95
1 Introduction……Page 97
2.1.1 Lithium……Page 99
2.1.2 Sodium……Page 100
2.1.3 Potassium……Page 101
2.2.1 Magnesium……Page 102
2.3.1 Aluminum……Page 104
2.3.4 Chromium……Page 105
2.3.6 Iron……Page 106
2.3.9 Copper……Page 108
2.3.10 Zinc……Page 109
2.3.13 Palladium……Page 110
2.3.18 Gold……Page 111
2.3.19 Mercury……Page 112
2.4.1 Uranium in Sea Water……Page 113
2.4.2 General Considerations and Problems……Page 115
2.4.3 Sorbent Materials……Page 119
2.4.3.1 Hydrous Titanium Oxide……Page 120
2.4.3.2 Poly(Acrylamidoxime)……Page 123
2.4.4.2 Poly(A crylamidoxime)……Page 125
2.4.5.1 Fixed Sorbent Beds……Page 126
2.4.5.2 Fluidized Sorbent Beds……Page 128
4 References……Page 133
Author Index Volumes 101-124……Page 138