Organosilicon chemistry II: from molecules to materials

Norbert Auner, Johann Weis3527292543, 9783527292547

Organosilicon Chemistry at its best… Like its hugely successful predecessor, this volume presents the latest developments in a rapidly developing field of industrial and academic research. Written by leading experts, it is a unique handbook for every scientist concerned with organosilicon compounds and their applications. From reviews of the first volume: ‘The excellent presentation of its contents guarantees that it will occupy a prominent place within the literature on silicon chemistry.’ Nachr. Chem. Lab. Techn. ‘… I do recommend this book highly to those scientists in academia and industry who are active in molecular organosilicon chemistry and/or silicon-based materials science.’ Synthesis

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Table of contents :
Cover Page……Page 1
Title Page……Page 4
ISBN 3527292543……Page 5
Preface……Page 6
Acknowledgement……Page 7
I Tetravalent Organosilicon Compounds: Chemistry and Structure……Page 8
II Organosubstituted Silicon with Unusual Coordination Numbers……Page 11
III Organosilicon Metal Compounds: Their Use in Organosilicon Synthesis, Coordination Chemistry, and Catalysis……Page 13
IV Silicon Polymers: Formation and Application……Page 15
Indexes……Page 17
List of Contributors……Page 18
I Tetravalent Organosilicon Compounds: Chemistry and Structure……Page 25
Small Organosilicon Molecules – Synthesis, Stereochemistry, and Reactivity……Page 27
Properties of Si-functionalized (Fluoromethyl)silanes……Page 43
Silicides as Catalysts for Hydrodehalogenation of Silicon Tetrachloride……Page 55
Silacyclobutenes – Synthesis and Reactivity……Page 65
Allyl Cleavage of 2-Silanorbornenes – A Facile Synthesis of Cyclopentenyl Compounds of Organochlorosilanes and of 2-Silanorbornanes……Page 73
Base-catalyzed Hydrogenation of Chlorosilanes by Organotin Hydrides……Page 79
The Catalytic Hydrogenation of Methylchlorodisilanes with Tri-nbutylstannane……Page 87
Disproportionation of Tetrachlorodimethyldisilane – NMR-Spectroscopic Identification of the Primary Products……Page 93
Cyclotrisilane and Silacyclopropane – An Equilibrium……Page 99
Synthesis and Spectroscopy of Phenylated and Halogenated Trisilanes and Disilanes……Page 105
Investigations Concerning the Electrochemical Formation of Di- and Polysilanes……Page 113
Syntheses, 29Si NMR Spectra, and Vibrational Spectra of Methylated Trisilanes……Page 119
New Ways to Difunctional Cyclosilanes……Page 125
New Polycyclic Si-Ring Systems……Page 129
Preparation and Reactions of Permethylated Cyclooligosilane Alkali Metal Derivatives……Page 133
Synthesis, Reactivity, and Spectroscopy of Phenylated Cyclotetrasilanes and Cyclopentasilanes……Page 137
Oligosilanylsulfanes: New Functional Derivatives of Higher Silicon Hydrides……Page 145
Synthesis and Reactions of Iminosilanes……Page 151
1,3-Diazabutadienes and Amidinates as Ligands to Silicon Centers……Page 157
Specific Insertion of O=C=S into the N-Si Bond of an Extremely Electron-rich Molecule as Evident from the X-Ray Crystal Structure……Page 165
Carbene and Carbenoid Chemistry of Silyldiazo acetic Esters: The Silyl Group as a Substituent and a Functional Group……Page 173
The Function of the Trimethylsilyl Substituent in the Syntheses of Low-valent Phosphorus and Arsenic Containing Compounds……Page 185
Silicon and Phosphinomethanides: Novel Heteroelement Substituted Methanes and Ylides……Page 211
Supersilyl Phosphorus Compounds……Page 219
Silicon-Phosphorus, -Arsenic, -Antimony, and -Bismuth Cages: Syntheses and Structures……Page 227
Synthesis, Reactivity, and Molecular Structure of Diphosphadisilacyclobutanes, Bis(stannyl)silyl-, and Bis(stannyl)germylphospines……Page 233
On the Reaction of Silanols with Alcohols……Page 239
4-Silyloxybenzothiopyrylium-Salts: A New Tool for the Stereoselective Annulation of S-Heterocycles……Page 243
Diastereoselective Synthesis of Annulated Quinolones by Transformations with 4-Silyloxyquinolinium-Salts……Page 249
Biological Recognition of Enantiomeric Silanes and Germanes: Syntheses and Antimuscarinic Properties of the Enantiomers of the Si/Ge Analogues……Page 255
Biotransformation as a Preparative Method for the Synthesis of Optically Active Silanes, Germanes, and Digermanes: Studies on the (R) Selective Microbial Reduction of MePh(Me3C)ElC(0)Me (El = Si, Ge),……Page 261
Aldehyde-functionalized Silanes: New Compounds to Improve the Immobilization of Biomolecules……Page 267
II Organosubstituted Silicon with Unusual Coordination Numbers……Page 273
Silylenes, Stable and Unstable……Page 275
Silylenes and Multiple Bonds to Silicon: Synergism between Theory and Experiment……Page 287
Heterosubstituted Silylenes: Cycloadditions with Heterodienes and -trienes……Page 313
Decomposition Products of Methyltrichlorosilane……Page 319
C2H2Si Isomers: Generation by Pulsed Flash Pyrolysis and Matrix-Spectroscopic Identification……Page 327
Silylene and Disilene Additions to the Double Bonds of Alkenes, 1,3-Dienes, and Hetero-l,3-dienes……Page 333
Generation of Silylenes and Silaethenes by Dehalogenation of Chlorosilanes……Page 341
Triple Bonds to Silicon: Substituted Silanitriles Versus Silaisonitriles – A Theoretical Study……Page 345
The Nature of Organosilicon Cations and Their Interactions……Page 353
NMR Spectroscopic Investigation of the β-Silyl Effect in Carbocations……Page 385
Underloaded and Overloaded Unsaturated Silicon Compounds……Page 391
The Synthesis of Transient Silenes using the Principle of the Peterson Reaction……Page 413
Cycloaddition Reactions of 1,1-Dichloro-2-neopentylsilene with Pentafulvenes……Page 423
Silaneimines……Page 429
Recent Explorations of the Chemistry of Pentacoordinate Silicon……Page 435
Syntheses, Structures, and Properties of Molecular λ5Si-Silicates Containing Bidentate 1,2-Diolato(2-) Ligands Derived from a-Hyd……Page 451
Syntheses and Solution-State NMR Studies of zwitterionic Spirocyclic λ5Si-Organosilicates Containing Two Identical Unsymmetrically Substituted 1,2-Benzenodiolato(2-) Ligands……Page 471
Ab Initio Studies of the Bis[ 1,2-benzenediolato(2-)]hydridosilicate( 1-) Ion……Page 477
Highly Coordinated Silicon Compounds – Hydrazino Groups as Intramolecular Donors……Page 483
III Organosilicon Metal Compounds: Their Use in Organosilicon Synthesis, Coordination Chemistry, and Catalysis……Page 491
Silicon Frameworks and Electronic Structures of Novel Solid Silicides……Page 493
Alkali Metal Derivatives of Tris(trimethylsilyl)silane – Syntheses and Molecular Structures……Page 517
Mono-, Bis-, Tris-, and Tetrakis(lithiomethyl)silanes: New Building Blocks for Organosilicon Compounds……Page 523
Neutral and Anionic Lithiumsilylamides as Precursors of Inorganic Ring Systems……Page 529
Lithium tButylamidosilanes – Syntheses and Structures……Page 535
Dilithiated Oligosilanes: Synthesis, Structure, and Reactivity……Page 543
Synthesis of Gallium Hypersilyl Derivatives……Page 549
New Organometallic Silicon-Chalcogen Compounds……Page 555
Alternative Ligands XXXII[1]l: Heterobimetallic Donor-Acceptor Interactions in Si/Ni-Cages: Metallosilatranes……Page 565
Reactivity of π-Coordinated Chlorocyclopentadienylsilanes……Page 571
CO-, Isonitrile-, and Phosphine-induced Silyl Migration Reactions in Heterobimetallic Fe-Pd and Fe-Pt Complexes……Page 577
Novel Diazomethylsilyl Substituted Fischer Carbene Complexes……Page 589
1-Metalla-2-sila-1,3-diene Compounds……Page 593
Novel Metallo-Silanols, -Silanediols, and -Silanetriols of the Iron and Chromium Group: Generation, Structural Characterization,……Page 599
Oligosilanyl-Tungsten Compounds-Precursors for Tungsten-Silicide CVD?……Page 609
IV Silicon Polymers: Formation and Application……Page 613
Silyl Modified Surfaces – New Answers to Old Problems……Page 615
Alkenyl Ethoxysilanes for the Synthesis of Silylester Functionalized Copolymers and Surface Modification……Page 633
Silicone Surfactants – Development of Hydrolytically Stable Wetting Agents……Page 637
Siloxanes Containing Vinyl Groups……Page 643
Investigations of Chemical Heterogeneity in Polydimethylsiloxanes using SFC, HPLC, and MALDI-MS……Page 649
Vulcanization Kinetics of Addition-cured Silicone Rubber……Page 657
Photo-crosslinked Polysiloxanes – Properties and Applications……Page 673
Cationic Photo-crosslinking of α,ω-terminated Disiloxanes……Page 679
Azo- and Triazene Modified Organosilicones as Polymeric Initiators for Graft Copolymers……Page 683
Core Shell Structures Based on Polyorgano Silicone Micronetworks Prepared in Microemulsion……Page 689
Precrosslinked Poly(organosiloxane) Particles……Page 697
Silsesquioxanes of Mixed Functionality – Octa[(3-chloropropyl)-npropyl-silsesquioxanes] and……Page 709
New Functionalized Silsesquioxanes by Substitutions and Cage Rearrangement of Octa[(3-chloropropyl)-silsesquioxane]……Page 715
Investigations on the Thermal Behavior of Silicon Resins by Thermoanalysis, 29Si NMR, and IR Spectroscopy……Page 721
Convenient Approach to Novel Organosilicon Polymers……Page 727
Silicon Carbide and Carbonitride Precursors via the Silicon-Silicon Bond Formation: Chemical and Electrochemical New Perspective……Page 733
Synthesis of Spinnable Poly(silanes/-carbosilanes) and Their Conversion into SiC Fibers……Page 743
Polymeric Silylcarbodiimides – Novel Route to Si-C-N Ceramics……Page 749
New Modified Polycarbosilanes……Page 757
Heteropolysiloxanes by Sol-Gel Techniques: Composite Materials with Interesting Properties……Page 761
Fumed Silica – Production, Properties, and Applications……Page 785
Poly(dimethylsiloxane) Chains at a Silica Surface……Page 803
A New Precursor for Amorphous Germanium Films……Page 839
Getting Light from Silicon: From Organosilanes to Light Emitting Nanocrystalline Silicon……Page 845
A Novel Liquid Xenon IR Cell Constructed from a Silicon Single Crystal……Page 861
Author Index (with page links)……Page 865
Subject Index (with page links)……Page 871