Catalysis and Automotive Pollution Control III, Proceedings of the Third International Symposium CAPo: C 3

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Series: Studies in Surface Science and Catalysis 96

ISBN: 0444820191, 9780444820198

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A. Frennet and J.-M. Bastin (Eds.)0444820191, 9780444820198

These proceedings are taken from the Third International Symposium (CAPoC3), held in Belgium, 1994, and are devoted to the use of catalysis for the depollution of exhaust gases of motor vehicles. It covers such areas as catalyst ageing and poisoning, and gasoline catalyst technologies.

Table of contents :
Content:
Foreword
Pages xiii-xiv
J.-M. Bastin, A. Frennet

Acknowledgments
Page xv
J.-M. Bastin, A. Frennet

Finacial support
Page xvi

Organizing Committee
Page xvii

Automotive and environment: Towards a global approach Original Research Article
Pages 3-13
Dominique Savey

Developments in gasoline reformulation and the enhancement of refinery mtbe production Original Research Article
Pages 15-32
K.P. de Jong, W. Bosch, T.D.B. Morgan

Internal combustion engines probable evolutions and trends Original Research Article
Pages 33-52
P. Eyzat

Laboratory data for three-way catalytic converter modelling Original Research Article
Pages 55-71
D. Schweich

Reactivity of steam in exhaust gas catalysis. part II: Sintering and regeneration of Rh and PtRh catalysts in propane oxidation Original Research Article
Pages 73-84
J. Barbier Jr., D. Duprez

An infrared study of CO and NO adsorption on Pt, Rh, Pd 3-way catalysts Original Research Article
Pages 85-96
R.L. Keiski, M. Härkönen, A. Lahti, T. Maunula, A. Savimäki, T. Slotte

Comparative behaviour of Pd supported catalysts for the reduction of NO by CO in the presence of gas complex mixture including O2, CO2, H2O and hydrocarbons Original Research Article
Pages 97-108
A. Lemaire, J. Massardier, H. Praliaud, G. Mabilon, M. Prigent

XPS/TPR study of the reducibility of M/CeO2 catalysts (M=Pt, Rh): Does junction effect theory apply? Original Research Article
Pages 109-122
J.P. Holgado, G. Munuera

Enahncement of the reaction of nitric oxide and carbon monoxide by hydrogen and water over platinum and rhodium-containing catalysts Original Research Article
Pages 123-135
R. Dümpelmann, N.W. Cant, D.L. Trimm

Simultaneous nox reduction and soot elimination from diesel exhaust on perovskite-type oxide catalysts Original Research Article
Pages 137-147
V. Duriez, L. Monceaux, P. Courtine

How a three-way catalyst is affected under transient conditions: A study of Pt-Rh/Al2O3 catalyst Original Research Article
Pages 149-161
C. Howitt, V. Pitchon, F. Garin, G. Maire

Comparison of Pt/MnOx/SiO2 and Pt/CoOx/SiO2 catalysts for the CO oxidation with O2 and the no reduction with CO Original Research Article
Pages 163-177
Y.J. Mergler, A. van Aalst, J. van Delft, B.E. Nieuwenhuys

Reduction behavior of Rh-Sn/SiO2 bimetallic catalysts and its co oxidation activity Original Research Article
Pages 179-191
Satoru Nishiyama, Ikuo Yamamoto, Masahiro Akemoto, Shigeru Tsuruya, Mitsuo Masai

Preparation of Pt-Rh/Al2O3-CeO2 catalysts by surface redox reactions Original Research Article
Pages 193-202
L. Pirault, D. El Azami El Idrissi, P. Marécot, J.M. Dominguez, G. Mabilon, M. Prigent, J. Barbier

Reactivity of perovskites as automotive converters Original Research Article
Pages 203-213
Laure Simonot, François Garin, Gilbert Maire

Effect of the CeO2 dispersion on alumina on its reactivity for co and no conversion Original Research Article
Pages 215-227
R. Cataluña, A. Arcoya, X.L. Seoane, A. Martínez-Arias, J.M. Coronado, J.C. Conesa, J. Soria, L.A. Petrov

Mechanism of chemical activation of Pt-Rh alloy and Pt/Rh bimetallic single crystal surfaces Original Research Article
Pages 229-236
Hiroyuki Tamura, Akira Sasahara, Ken-ichi Tanaka

Changes in microstructure and catalytic activity effected by redox cycling of rhodium upon CeO2 and Al2O3 Original Research Article
Pages 237-248
J. Cunningham, D. Cullinane, F. Farrell, M.A. Morris, A. Datye, D. Lalakkad

Catalytic oxidation of propane over palladium supported on alumina aerogel. Effects of the pretreatment on the activity and investigation of the state of palladium by grazing-incidence-x-ray diffraction Original Research Article
Pages 249-259
C. Hoang-Van, R. Harivololona, S. Fayeulle

Characterization of surface and bulk oxygen species of three way catalysts by O2 TPD and H2 TPR Original Research Article
Pages 261-274
C. Bouly, K. Chandes, D. Maret, D. Bianchi

The oxidation of carbon monoxide by oxygen over polycrystalline platinum, palladium and rodium from UHV to normal pressure Original Research Article
Pages 275-284
S. Fuchs, T. Hahn

Oxidation and disproportionation of carbon monoxide over Pd-ZrO2 catalysts prepared from glassy Pd-Zr alloy and by coprecipitation Original Research Article
Pages 285-295
S. Gredig, S. Tagliaferri, M. Maciejewski, A. Baiker

Combustion of M-xylene over Pd catalysts derived from amorphous Pd2Ni50Nb48 alloy Original Research Article
Pages 297-303
László Borkó, Hua Zhu, Zoltán Schay, István Nagy, Antal Lovas, László Guczi

Design and performance of a ceramic preconverter system Original Research Article
Pages 307-323
S.T. Gulati, L.S. Socha, P.M. Then

Improvement of the thermal stability of ceria support Original Research Article
Pages 325-334
M. Pijolat, M. Prin, M. Soustelle, O Touret, P. Nortier

Radial flow converter: New developments in high cell density catalysts Original Research Article
Pages 335-346
F. Bonnefoy, F. Petitjean, P. Steenackers

Stabilization of rhodium/alumina catalysts by silicon exchange Original Research Article
Pages 347-360
R.W. McCabe, R.K. Usmen, G.W. Graham, W.L.H. Watkins, W.G. Rothschild

Structural, morphological and surface chemical features of Al2O3 catalyst supports stabilized with CeO2 Original Research Article
Pages 361-373
C. Morterra, G. Magnacca, V. Bolis, G. Cerrato, M. Baricco, A. Giachello, M. Fucale

Support and nemca induced promotional effects on the activity of automotive exhaust catalysts Original Research Article
Pages 375-385
I.V. Yentekakis, C.A. Pliangos, V.G. Papadakis, X.E. Verykios, C.G. Vayenas

Synthesis and study of honeycomb monolithic catalysts for catalytic combustion Original Research Article
Pages 387-392
Z.R. Ismagilov, G.V. Chernykh, R.A. Shkrabina

Structure and catalytic activity of mixed oxides of perovskite structure Original Research Article
Pages 393-404
V. Mathieu-Deremince, J.B. Nagy, J.J. Verbist

Preparation of alumina supported ceria. I: Selective measurement of the surface area of ceria and free alumina Original Research Article
Pages 405-418
R. Fréty, P.J. Lévy, V. Perrichon, V. Pitchon, M. Primet, E. Rogemond, N. Essayem, M. Chevrier, C. Gauthier, F. Mathis

Influence of the nature of the metal precursor salt on the redox behaviour of ceria in Rh/CeO2 catalysts Original Research Article
Pages 419-429
S. Bernal, J.J. Calvino, G.A. Cifredo, J.M. Gatica, J.A. Pérez Omil, A. Laachir, V. Perrichon

The preparation of thermally stable washcoat aluminas from low cost gibbsite Original Research Article
Pages 431-437
Yafeng Huang, N.W. Cant, J. Guerbois, D.L. Trimm, A. Walpole

Development of improved Pd-only and Pd/Rh three-way catalysts Original Research Article
Pages 441-460
B.H. Engler, D. Lindner, E.S. Lox, A. Schäfer-Sindlinger, K. Ostgathe

Smart Pd TWC technology to meet stringent standards Original Research Article
Pages 461-472
J. Dettling, Z. Hu, Y.K. Lui, R. Smaling, C.Z. Wan, A. Punke

A palladium front brick study Original Research Article
Pages 473-485
Douglas J. Ball, Etienne Jacque

Non-noble metal environmental catalysts: Synthesis, characterization and catalytic activity Original Research Article
Pages 487-496
Philip G. Harrison, Nicholas C. Lloyd, Wan Azelee

Catalytic oxidation of diesel particulates with base metal oxides Original Research Article
Pages 499-515
K.E. Voss, J.K. Lampert, R.J. Farrauto, G.W. Rice, A. Punke, R. Krohn

Performance of oxidation catalysts for heavy-duty diesel engines Original Research Article
Pages 517-528
H.J. Stein, G. Hüthwohl, G. Lepperhoff

Catalytic reduction of nitrogen oxides in diesel exhaust gas Original Research Article
Pages 529-547
B.H. Engler, J. Leyrer, E.S. Lox, K. Ostgathe

Catalytic oxidation of diesel soot: Catalyst development Original Research Article
Pages 549-561
John P.A. Neeft, Olaf P. van Pruissen, Michiel Makkee, Jacob A. Moulijn

Catalytic combustion of diesel soot on perovskite type oxides Original Research Article
Pages 563-574
W. Sri Rahayu, L. Monceaux, B. Taouk, P. Courtine

The mechanism of the lean Nox reaction over Pt-based catalysts Original Research Article
Pages 577-590
G.P. Ansell, S.E. Golunski, J.W. Hayes, A.P. Walker, R Burch, P.J. Millington

Influence of the copper dispersion on the selective reduction of nitric oxide over Cu/Al2O3: Nature of the active sites Original Research Article
Pages 591-604
Z. Chajar, M. Primet, H. Praliaud, M. Chevrier, C. Gauthier, F. Mathis

Lean NOx reduction on Cu-NaY and Cu-HZSM5 zeolites at the spark ignition engine exhaust Original Research Article
Pages 605-617
P. Ciambelli, P. Corbo, M. Gambino, V. Indovina, G. Moretti, M.C. Campa

Oxidation state of copper during the reduction of NOx with propane on H-Cu-ZSM-5 in excess oxygen Original Research Article
Pages 619-629
T. Pieplu, F. Poignant, A. Vallet, J. Saussey, J.C. Lavalley, J. Mabilon

No decomposition over partially reduced metallized CeO2 containing catalysts Original Research Article
Pages 631-643
Gangavarapu Ranga Rao, Paolo Fornasiero, Jan Kašpar, Sergio Meriani, Roberta Di Monte, Mauro Graziani

Selective catalytic reduction of NOx in diesel exhaust gases with NH3 over Ce & Cu mordenite and V2O5/TiO2/WO3 type catalysts: Can Ce solve the NH3 slip problem? Original Research Article
Pages 645-653
R.J. Hultermans, E. Ito, Á József, P.M. Lugt, C.M. van den Bleek

Reaction study of diesel exhaust gases over copper oxide based model catalysts Original Research Article
Pages 655-660
C.M. Pradier, H. Vikström, J. Paul

Selective reduction of NOx with ammonia over cerium exchanged zeolite catalysts: Towards a solution for an ammonia slip problem Original Research Article
Pages 661-673
E. Ito, R.J. Hultermans, P.M. Lugt, M.H.W. Burgers, H. van Bekkum, C.M. van den Bleek

Selective reduction of no over copper-containing modified zeolites Original Research Article
Pages 675-685
J. Halász, J. Varga, G. Schöbel, I. Kiricsi, K. Hernádi, I. Hannus, K. Varga, P. Fejes

Zeolite catalyst for the purification of automotive exhaust gases Original Research Article
Pages 687-696
Delia Florea, Lucia Georgescu, Floreta Constantinescu, Dumitru Mãnoiu, Dinu Gaber, Mihaela Comãnescu

Studies of selective no reduction by CH4 and CH3OH over Co and Cu exchanged mordenite Original Research Article
Pages 697-706
J. Vassallo, M. Lezcano, E. Miró, J. Petunchi

Sepiolite based monolithic catalysts for the reduction of nitric oxide with propylene in oxidising atmosphere Original Research Article
Pages 707-717
P. Avila, J. Blanco, J.M.R. Blas, O. Ruiz de los Paños, M. Yates

Impact of sulfur on three-way catalysts: Comparison of commercially produced Pd and Pt-Rh monoliths Original Research Article
Pages 721-748
D.D. Beck, John W. Sommers

An X-ray absorption spectroscopic investigation of aged automotive catalysts Original Research Article
Pages 749-762
F. Maire, M. Capelle, G. Meunier, J.F. Beziau, D. Bazin, H. Dexpert, F. Garin, J.L. Schmitt, G. Maire

Sulfur adsorption and desorption on fresh and aged Ce containing catalysts Original Research Article
Pages 763-774
S. Lundgren, G. Spiess, O. Hjortsberg, E. Jobson, I. Gottberg, G. Smedler

Inhibition of post-combustion catalysts by alkynes: A clue for understanding their behaviour under real exhaust conditions Original Research Article
Pages 775-788
G. Mabilon, D. Durand, Ph. Courty

Metal surface area measurement of fresh and aged automotive catalysts by CO methanation Original Research Article
Pages 789-799
R.K. Usmen, R.W. McCabe, M. Shelef

Effects of sintering and of additives on the oxygen storage capacity of PtRh catalysts Original Research Article
Pages 801-811
D. Martin, R. Taha, D. Duprez

Study of hydrocarbons removal with a three-way automotive catalyst after severe thermal aging Original Research Article
Pages 813-828
J.M. Bart, M. Prigent, A. Pentenero

Simultaneous atmosphere and temperature cycling of three-way automotive exhaust catalysts Original Research Article
Pages 829-839
S. Humbert, A. Colin, L. Monceaux, F. Oudet, P. Courtine

The effect of “spark retard” as a method of raising exhaust gas temperature for automotive catalyst dyno ageing Original Research Article
Pages 841-852
J Kisenyi, N Pallin, C Tooby, R.G. Hurley, P Atherton, D Webb

Control of unregulated emmissions from ethanol-fluelled diesel engines—A study of the effect of catalyst support on the low temperature oxidation of ethanol and acetaldehyde using precious metals Original Research Article
Pages 855-869
L.J. Pettersson, S.G. Järs, S. Andersson, P. Marsh

Catalysts for natural gas emission control applications Original Research Article
Pages 871-884
R.G. Silver, J.C. Summers

Modelling three-way monolithic catalytic converter: Comparison between simulation and experimental data Original Research Article
Pages 887-895
S. Siemund, D. Schweich, J.P. Leclerc, J. Villermaux

Behaviour of three-way catalysts in a hybrid drive system: Dynamic measurements and kinetic modelling Original Research Article
Pages 897-908
S. Tagliaferri, L. Padeste, A. Baiker

The performance of a monolithic catalytic converter of automobile exhaust gas with oscillatory feeding of Co, No, and O2: A modelling study Original Research Article
Pages 909-918
A.J.L. Nievergeld, J.H.B.J. Hoebink, G.B. Marin

Cold start hydrocarbon emissions control via admixing three way conversion catalysts with heat exchange and hydrocarbon adsorption phenomena Original Research Article
Pages 919-930
P.L. Burk, J.K. Hochmuth, D.R. Anderson, S. Sung, A. Punke, U. Dahle, S.J. Tauster, C.O. Tolentino, J. Rogalo, G. Miles, M. Mignano, M. Niejako

Author index
Pages 931-934

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