Modern Electrochemistry

Bockris J.O., Reddy A.0-306-47605-3, 0-306-46166-8

Table of contents :
CONTENTS……Page 16
INDEX……Page 30
6.1. ELECTRIFICATION OF AN INTERFACE……Page 54
6.2. EXPERIMENTAL TECHNIQUES USED IN STUDYING INTERFACES……Page 65
6.3. THE POTENTIAL DIFFERENCE ACROSS ELECTRIFIED INTERFACES……Page 89
6.4. THE ACCUMULATION AND DEPLETION OF SUBSTANCES AT AN INTERFACE……Page 125
6.5. THE THERMODYNAMICS OF ELECTRIFIED INTERFACES……Page 131
6.6. THE STRUCTURE OF ELECTRIFIED INTERFACES……Page 154
6.7. STRUCTURE AT THE INTERFACE OF THE MOST COMMON SOLVENT: WATER……Page 178
6.8. IONIC ADSORPTION……Page 202
6.9. THE ADSORPTION PROCESS OF ORGANIC MOLECULES……Page 251
6.10. THE STRUCTURE OF OTHER INTERFACES……Page 267
6.11. DOUBLE LAYERS BETWEEN PHASES MOVING RELATIVE TO EACH OTHER……Page 289
EXERCISES……Page 298
PROBLEMS……Page 303
MICRO RESEARCH PROBLEMS……Page 312
APPENDIX 6.1. MEASUREMENT OF THE ELECTRODE-SOLUTION VOLTA POTENTIAL DIFFERENCE……Page 314
7.1. INTRODUCTION……Page 318
7.2. ELECTRON TRANSFER UNDER AN INTERFACIAL ELECTRIC FIELD……Page 325
7.3. A MORE DETAILED LOOK AT SOME QUANTITIES IN THE BUTLER-VOLMER EQUATION……Page 350
7.4. ELECTRODE KINETICS INVOLVING THE SEMICONDUCTOR/SOLUTION INTERFACE……Page 357
7.5. TECHNIQUES OF ELECTRODE KINETICS……Page 374
7.6. MULTISTEP REACTIONS……Page 449
7.7. THE INTERMEDIATE RADICAL CONCENTRATION, AND ITS EFFECT ON ELECTRODE KINETICS……Page 476
7.8. THE REACTIVITY OF CRYSTAL PLANES OF DIFFERING ORIENTATION……Page 484
7.9. TRANSPORT IN THE ELECTROLYTE EFFECTS CHARGE TRANSFER AT THE INTERFACE……Page 494
7.10. HOW TO DETERMINE THE STEPWISE MECHANISMS OF ELECTRODIC REACTIONS……Page 540
7.11. ELECTROCATALYSIS……Page 558
7.12. THE ELECTROGROWTH OF METALS ON ELECTRODES……Page 576
7.13. CURRENT-POTENTIAL LAWS FOR ELECTROCHEMICAL SYSTEMS……Page 631
7.14. THE ELECTROCHEMICAL ACTIVATION OF CHEMICAL REACTIONS……Page 654
7.15. ELECTROCHEMICAL REACTIONS THAT OCCUR WITHOUT INPUT OF ELECTRICAL ENERGY……Page 657
7.16. THE ELECTROCHEMICAL HEART……Page 663
8.1. INTRODUCTION……Page 684
8.2. GALVANOSTATIC TRANSIENTS……Page 692
8.3. OPEN-CIRCUIT DECAY METHOD……Page 695
8.4. POTENTIOSTATIC TRANSIENTS……Page 697
8.5. OTHER MATTERS CONCERNING TRANSIENTS……Page 699
8.6. CYCLIC VOLTAMMETRY……Page 705
8.7. LINEAR SWEEP VOLTAMMETRY FOR REACTIONS THAT INCLUDE SIMPLE ADSORBED INTERMEDIATES……Page 721
FURTHER READING……Page 725
EXERCISES……Page 726
PROBLEMS……Page 730
MICRO RESEARCH PROBLEMS……Page 735
9.1. SETTING THE SCENE……Page 738
9.2. CHEMICAL POTENTIALS AND ENERGY STATES OF “ELECTRONS IN SOLUTION”……Page 741
9.3 POTENTIAL ENERGY SURFACES AND ELECTRODE KINETICS……Page 756
9.4. TUNNELING……Page 772
9.5. SOME ALTERNATIVE CONCEPTS AND THEIR TERMINOLOGY……Page 779
9.6. A QUANTUM MECHANICAL DESCRIPTION OF ELECTRON TRANSFER……Page 782
9.7. FOUR MODELS OF ACTIVATION……Page 794
9.8. BOND-BREAKING REACTONS……Page 801
9.9. A QUANTUM MECHANICAL FORMULATION OF THE ELECTROCHEMICAL CURRENT DENSITY……Page 804
9.10. A RETROSPECT AND PROSPECT FOR QUANTUM ELECTROCHEMISTRY……Page 805
Further Readings……Page 806
APPENDIX. THE SYMMETRY FACTOR; DO WE UNDERSTAND IT?……Page 809
EXERCISES……Page 813
PROBLEMS……Page 815
MICRO RESEARCH PROBLEM……Page 817